Ultra-fast charge-discharge and high energy storage density realized in NaNbO3–La(Mn0.5Ni0.5)O3 ceramics
Lead-free antiferroelectric (AFE) NaNbO 3 (NN) is one of promising materials for dielectric capacitors, but the recoverable energy-storage density and efficiency get restrained owing to huge remanent polarization and limited dielectric breakdown field strength . In this work, a variety of NN based lead-free bulk (1- x )NaNbO 3 - x La(Mn 0.5 Ni 0.5 )O 3 (abbreviated as (1- x )NN- x LMN, x = 0, 0.05, 0.10, 0.15, 0.20) ceramics were designed using a solid-state synthesis method. Remarkably, an ultra-fast charge-discharge speed 47 ns and an acceptable recoverable energy-storage density W rec ~1.77 J/cm 3 with a high efficiency η = 77% were obtained under the E b of 200 kV/cm at x = 0.05. The superior energy storage performance is attributed to the regulation of domain size and voltage resistance by special ions substitution of A and B sites. This work not only proposes an efficient strategy to realize high recoverable energy-storage density and efficiency, but also provide an candidate material for application of advanced pulsed power capacitors.
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