The cathode of solid oxide electrolysis cell (SOEC) is used as a place for fuel gas electrolysis/co-electrolysis, and its performance significantly affects the efficiency of electrolysis. La 0.75 Sr 0.25 Cr 0.5 Mn 0.5 O 3-δ (LSCM) is a potential SOEC cathode material due to its excellent redox stability and catalytic ability for fuel gas. An electrolyte-supported LSCM/YSZ/LSCM symmetrical cell and LSCM/YSZ/LSCF full cell were prepared and evaluated for high temperature steam electrolysis, carbon dioxide electrolysis and co-electrolysis. Under the applied voltage, both the symmetrical electrolysis cell and the full electrolysis cell can effectively electrolysis CO 2 and H 2 O. During the experiment, by changing the operating conditions, the influence of different temperatures, concentration of CO 2 and H 2 O, and applied voltage was studied to evaluate the electrochemical performance of SOEC. In order to further verify the long-term performance of SOEC, constant voltage was applied for co-electrolysis of CO 2 and H 2 O. During the entire electrolysis process, the SOEC showed a stable current density of 0.1A·cm -2 under the applied voltage 1.5 V for more than 24 h.
Surface and interface engineering as an efficient and controllable strategy in designing electrode structure has been widely investigated for achieving high catalyst activity and durability of robust electrodes in solid oxide cells (SOCs). The constructed heterojunction structures favor expedited charge transfer and promote the catalytic reaction. Anti-coking La 0.75 Sr 0.25 Cr 0.5 Mn 0.5 O 3-δ (LSCM)-based fuel electrodes are considered as promising candidates for alternative Ni-based cermet electrodes in solid oxide electrolysis cell (SOEC), however, they suffer from insufficient electrocatalytic activity for CO 2 electrolysis. Herein, Mn-containing Pr 0.6 Sr 0.4 FeO 3-δ (Pr 0.6 Sr 0.4 Fe 0.8 Mn 0.2 O 3-δ , PSFM) nanoparticles with excellent catalyst activity are synthesized and epitaxially grown on the surface of LSCM via infiltration technique. The spontaneous connected interface can provide direct tunnel for oxygen ion and electron transport along the (110) plane of LSCM. Meanwhile, this interface promotes an increase in oxygen vacancies and enhances both surface oxygen exchange and bulk oxygen diffusion capacities. These improvements are advantageous for CO 2 adsorption and carbonate dissociation at three phase boundaries (TPBs), leading to a significant enhancement in the kinetics of CO 2 reduction reaction. The electrolyte-supported single with PSFM/La 0.75 Sr 0.25 Cr 0.5 Mn 0.5 O 3-δ -Gd 0.1 Ce 0.9 O 2-δ (LSCM-GDC) fuel electrode exhibits an impressive current density of 1.09 A cm −2 at the applied voltage of 1.5 V and 800 °C, which increases by approximately 336 % than that of LSCM-GDC. In addition, the atomic arrangement enables in-situ formation of PSFM by trapping of surface Sr/Mn atoms on the LSCM surface, avoiding Sr segregation and enhancing the resistance to sulfur poisoning. This study demonstrates a strategy for achieving the enhanced CO 2 electrolysis performance and sulfur tolerance by engineering highly active interface.
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