Lihong Gao,Zhuang Ma,Song Wang,Fuchi Wang,Cai Yang
La1−xSrxTiO3+δhas attracted much attention as an important perovskite oxide. However, there are rare reports on its optical properties, especially reflectivity. In this paper, its structural and optical properties were studied. The X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy and spectrophotometer were used to characterize the sample. The results show that with increasing Sr concentration, the number of TiO6octahedral layers in each “slab” increases and the crystal structure changes from layered to cubic structure. A proper Sr doping (x= 0.1) can increase the reflectivity, reaching 95% in the near infrared range, which is comparable with metal Al measured in the same condition. This indicates its potential applications as optical protective coatings or anti-radiation materials at high temperatures.Keywords:perovskite structure;La1−xSrxTiO3+δ;structural property;reflectivity
Jing Kong,Lihong Gao,Zhuang Ma,Fu Chi Wang,Li Ao Yue
La1-xSrxTiO3+δ (LST) has been studied in many fields due to its excellent physical and chemical properties. However, there are rare reports on its optical properties, especially reflectivity. Our previous work has prepared LST coatings by atmospheric plasma spraying technique, but the reflectivity is much lower than that of LST powder itself. In this paper, LST coating was prepared by knife coating which is a traditional convenient method. The phase structure and surface morphology of the coating were examined by X-ray diffraction and scanning electron microscopy, respectively. The optical property was characterized by UV-visible-near infrared spectroscopy and the laser ablation tests were carried out by YSL-2000 Fiber Laser (IPG Co) with the wavelength of 1070 nm and the spot size of 10 mm×10 mm. Results show that the reflectivity of the LST coatings depends on the weight ratio of LST and binder. A high-reflectivity coating can be prepared by knife coating with appropriate content of LST.