Synergistic effect of HCl and NO in elemental mercury catalytic oxidation over La2O3-TiO2 catalyst
Elemental mercury (Hg 0 ) oxidation over a low-temperature La 2 O 3 -TiO 2 (LaTi) catalyst through a fixed-bed reactor system is reported here. Despite the presence of oxygen (O 2 ), Hg 0 was not effectively oxidized by either hydrogen chloride (HCl) or nitrogen oxide (NO). However, Hg 0 oxidation over the LaTi catalyst was greatly improved when both HCl and NO were present in the simulated flue gas. Several methods, including X-ray photoelectron spectroscopy (XPS), diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy, and temperature-programmed decomposition (TPD), were used to study the inherent mechanisms involved in the Hg 0 oxidation by HCl and NO. The results indicated that the combined presence of HCl and NO exhibited great synergy for Hg 0 catalytic oxidation over the LaTi catalyst. The reaction mechanism is proposed as follows: 1) NO was adsorbed and oxidized on the catalyst surface, forming NO 2 ; 2) the reactive NO 2 then oxidized gas phase Hg 0 to mostly HgO, and; 3) HgO reacted with gas phase HCl to produce HgCl 2 , which escaped from the catalyst’s surface. Differing from previously proposed mechanisms, La 2 O 3 was first studied as an active substance in Hg 0 oxidation. These findings are beneficial for those seeking economical and efficient Hg 0 oxidation catalysts for coal-fired power plants.
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