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Mn2+-activated dual-wavelength emitting materials toward wearable optical fibre temperature sensor

Song Enhai,Chen Meihua,Chen Zitao,Zhou Yayun,Zhou Weijie,Sun Hong-Tao,Yang Xianfeng,Gan Jiulin,Ye Shi,Zhang Qinyuan

Photothermal sensing is crucial for the creation of smart wearable devices. However, the discovery of luminescent materials with suitable dual-wavelength emissions is a great challenge for the construction of stable wearable optical fibre temperature sensors. Benefiting from the Mn 2+ -Mn 2+ superexchange interactions, a dual-wavelength (530/650 nm)-emitting material Li 2 ZnSiO 4 :Mn 2+ is presented via simple increasing the Mn 2+ concentration, wherein the two emission bands have different temperature-dependent emission behaviours, but exhibit quite similar excitation spectra. Density functional theory calculations, coupled with extended X-ray absorption fine structure and electron-diffraction analyses reveal the origins of the two emission bands in this material. A wearable optical temperature sensor is fabricated by incorporating Li 2 ZnSiO 4 :Mn 2+ in stretchable elastomer-based optical fibres, which can provide thermal-sensitive emissions at dual- wavelengths for stable ratiometric temperature sensing with good precision and repeatability. More importantly, a wearable mask integrated with this stretchable fibre sensor is demonstrated for the detection of physiological thermal changes, showing great potential for use as a wearable health monitor. This study also provides a framework for creating transition-metal-activated luminescence materials.