Co-doped modified LiLuF4:Eu microcrystalline scintillator-based flexible film for high resolution X-ray imaging
X-ray detectors based on scintillators are widely used in the fields of medical imaging, high-energy physics, geological exploration, and industrial detection. The development of scintillation materials with different characteristics has become the focus of considerable research interest. Herein, we report a facile hydrothermal synthesis of Gd- and Eu-codoped LiLuF4 microcrystals (MCs), which exhibit strong luminescence of Eu3+ ion characteristic emission, characterized by distinct red fluorescence emission. The research shows that Gd3+ co-doping effectively improved the sensitivity and light yield of LiLuF4:Eu MCs by regulating the proportion of co-doping ions. In addition, the detection limit is 140.72 nGy s−1 for LiLuF4:Eu,Gd MCs, approximately 39 times lower than the dose requirement of medical diagnosis. Based on LiLuF4:Eu,Gd MCs with the superior scintillation properties, a MC-composited film with 250 μm thickness was prepared by a direct coating method. The uniform and high-loading scintillation film exhibits outstanding imaging performance with a high spatial resolution of 14.8 LP mm−1, which confirms the application potential of X-ray imaging.
危险品化学品经营许可证（带存储）