Desalination and Water Treatment
·
2015
·
IF 1.173
Ling Li,Li Jun Yuan,Wei Hong,Lu Fan,Le Bao Mao,Li Liu
The adsorptions of methylene blue (MB) and methyl violet (MV) from an aqueous solution of Fe3O4/metal-organic frameworks (MOFs) composite were studied in view of the adsorption isotherm, kinetics and regenerate of the sorbent. The adsorption isotherms of MB and MV on Fe3O4/MOFs composite both followed the Langmuir isotherm. Adsorption kinetics were determined from the experimental data. The used Fe3O4/MOFs could be regenerated by acetonitrile, so it can be recycled for use. The excellent adsorption effect and reusability make Fe3O4/MOFs attractive for the removal of MB and MV from aqueous solution. The feasibility of Fe3O4/MOFs for application in magnetic solid-phase extraction was examined.
研究领域:
环境科学
·
材料科学
✓ 已验证
DOI
高影响因子
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
·
2017
·
IF 2.714
Zhennan Shi,Chen Xu,Han Guan,Ling Li,Lu Fan,Yingxi Wang,Li Liu,Qingtao Meng,Run Zhang
We designed and synthesized a magnetic metal organic frameworks (MOFs) composite, Cu-MOFs/Fe 3 O 4 as the adsorbent for removal of lead (Pb(II)) and malachite green (MG) in wastewater. This Cu-MOFs/Fe 3 O 4 can be easily prepared by in-situ growth of Cu-MOFs with doping Fe 3 O 4 nanoparticles . The prepared Cu-MOFs/Fe 3 O 4 composite was well characterized by SEM , XRD , and FTIR spectra. The adsorption experiments found that Cu-MOFs/Fe 3 O 4 can serve as adsorbent for removal of Pb(II) and MG simultaneously. The adsorption capacities were found to be 113.67 mg/g for MG and 219.00 mg/g for Pb 2+ , respectively, which are significantly higher than reported materials. Adsorption isotherm , kinetics and recyclability of Cu-MOFs/Fe 3 O 4 for removal of Pb(II) and MG were then studied. Adsorption of Pb(II) and MG exhibited Freundlich adsorption isotherm model, with the adsorption kinetics of available second-order kinetic. Physical adsorption for MG and chemical adsorption for Pb(II) were confirmed by Dubinin-Radushkevich (D-R) isothermal adsorption model. The adsorption of Pb(II) and MG in real water samples were then studied. The Fe 3 O 4 /Cu-MOFs was found to be recyclable for removal of Pb(II) and MG, can be explored as the potential adsorbent for waste water treatment.
研究领域:
环境科学
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
ACS Applied Materials & Interfaces
·
2023
·
IF 9.5
Wen-Qing Ding,Lei Xu,Xiao-Ying Li,Ming-Lai Fu,Baoling Yuan
Metal–organic frameworks (MOFs) are emerging as advanced nanoporous materials to remove phenylarsenic acid, p-arsanilic acid (p-ASA), and roxarsone (ROX) in the aqueous solution, while MOFs are often present as powder state and encounter difficulties in recovery after adsorption, which greatly limit their practical application in the aqueous environments. Herein, MIL-101 (Fe), a typical MOF, was mixed with sodium alginate and gelatin to prepare MIL-101@CAGE by three-dimensional (3D) printing technology, which was then used as a separatable adsorbent to remove phenylarsenic acid in the aqueous solution. The structure of 3D-printed MIL-101@CAGE was first characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FTIR), and thermogravimetry and differential thermogravimetry (TG-DTG). The octahedral morphology of MIL-101 (Fe) was found unchanged during the 3D printing process. Then, the adsorption process of MIL-101@CAGE on phenylarsenic acids was systematically investigated by adsorption kinetics, adsorption isotherms, adsorption thermodynamics, condition experiments, and cyclic regeneration experiments. Finally, the adsorption mechanism between MIL-101@CAGE and phenylarsenic acid was further investigated. The results showed that the Langmuir, Freundlich, and Temkin isotherms were well fit, and according to the Langmuir fitting results, the maximum adsorption amounts of MIL-101@CAGE on p-ASA and ROX at 25 °C were 106.98 and 120.28 mg/g, respectively. The removal of p-ASA and ROX by MIL-101@CAGE remained stable over a wide pH range and in the presence of various coexisting ions. The regeneration experiments showed that the 3D-printed MIL-101@CAGE could still maintain a more than 90% removal rate after five cycles. The adsorption mechanism of this system might include π–π stacking interactions between the benzene ring on the phenylarsenic acids and the organic ligands in MIL-101@CAGE, hydrogen-bonding, and ligand-bonding interactions (Fe–O–As). This study provides a new idea for the scale preparation of a separatable and recyclable adsorbent based on MOF material for the efficient removal of phenylarsenic acid in the aqueous solution.
研究领域:
环境科学
·
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
·
2018
·
IF 3.141
Yan Li,Jiangtao Liu,Kehu Zhang,Lei Lei,Zhongli Lei
A hybrid polymer–MOFs architecture UiO-66-NH2@PMAA was synthesized by tethering polymethacrylic acid (PMAA) onto the surface of the metal–organic frameworks UiO-66-NH2, and it was further employed for pectinase immobilization by electrostatic interactions. The hybrid architecture was prepared through a combination of atom transfer radical polymerization (ATRP), click chemistry and postsynthetic modification (PSM). The optimal immobilization parameters were at 25 °C and pH 4.0 with 10 U/mL of pectinase for 2 h, under which pectinase showed the highest enzymatic activity (1.215 U/mg) and protein loading (448.5 mg/g), respectively. Compared with free pectinase, the immobilized was found to exhibit higher pH, thermo, and storage stability. Additionally, the immobilized pectinase had remarkable reusability, the residual activity reached as high as 81% after 8 cycles continuously. Meanwhile, the desorption of immobilized pectinase can be achieved by changing pH values of the medium. Obviously, the UiO-66-NH2@PMAA with attractive properties is highly promising for enzyme immobilization.
研究领域:
生物化学
·
材料科学
✓ 已验证
DOI
高影响因子
DESALINATION
·
2022
·
IF 11.211
Fan Xiao,Ming Cao,Yingbo Chen
This work reported the successful preparation of a novel nano-Turing structure polyamide membrane. By introducing polyvinylpyrrolidone (PVP) into UiO-66-NH 2 , PVP-UiO-66-NH 2 with high water hydrophilicity and low particle size was synthesized. The aqueous phase dispersion containing PVP-UiO-66-NH 2 was loaded on the support through vacuum filtration method, and PVP-UiO-66-NH 2 was fused in the polyamide layer via traditional interfacial polymerization (IP) technology . The existence of PVP-UiO-66-NH 2 induced the occurrence of “local activation and lateral inhibition” in the IP system, resulting in the appearance of nano-Turing structure on the membrane surface . The successful preparation of PVP-UiO-66-NH 2 @polyamide composite membrane with uniform distribution of PVP-UiO-66-NH 2 was proved. The PVP-UiO-66-NH 2 @polyamide composite membrane showed excellent water permeability of 32.95 L·m −2 ·h −1 ·bar −1 and stable Na 2 SO 4 removal rate of 99.35 %, compared with 17.56 L·m −2 ·h −1 ·bar −1 and 99.56 % of pure polyamide membrane under the same conditions. In addition, the PVP-UiO-66-NH 2 @polyamide composite membrane exhibited excellent long-term filtration stability, thermal stability and antibacterial property .
研究领域:
材料科学
·
环境工程
✓ 已验证
产品关联
DOI
高影响因子
CHEMOSPHERE
·
2024
·
IF 8.1
Xiaoqian Zhang,Ze Zhu,Zhenfeng Guo,Ziting Huang,Xinhua Zheng,Xinqiang Wang,Luyi Zhu,Guanghui Zhang,Benxue Liu,Dong Xu
Iron-containing MOFs have attracted extensive interest as promising Fenton-like catalysts. In this work, magnetic Fe 3 O 4 nanofiber (FNS)/MOFs composites with stable structure, included FNS/MIL-88B, FNS/MIL-88A and FNS/MIL-100, were prepared via the in-situ solvothermal method . The surface of the obtained fibers was covered by a dense and continuous MOFs layer, which could effectively solve the agglomeration problem of MOFs powder and improved the catalytic performance. The adsorption and catalytic properties of FNS/MOFs composites were evaluated by removal of norfloxacin . FNS/MIL-88B showed the best performance with a maximum adsorption capacity up to 214.09 mg/g, and could degrade 99% of NRF in 60 min. Meanwhile, FNS/MIL-88B had a saturation magnetization of 20 emu/g, and could be rapidly separated by an applied magnetic field . The self-supported nanofibers allowed the adequate contact between MOFs and pollutants, and promoted the catalytic activity and high stability. We believe that this work provided a new idea for the design and preparation of Fenton-like catalysts especially MOFs composites.
研究领域:
环境科学
·
材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Journal of CO2 Utilization
·
2022
·
IF 8.321
Chengyuan Duan,Yuming Xie,Meili Ding,Yi Feng,Jianfeng Yao
Integrating dual Lewis acid and base as well as rational hierarchical pore structure in one catalyst is favorable to significantly boost the CO 2 cycloaddition reaction at mild conditions. In this regard, carbonized melamine sponge (CMS) featuring a highly porous network, rich nitrogen doping and excellent photothermal capability is employed as the ideal host for the construction of CMS@MOFs (namely, MIL-88-NH 2 and ZIF-8-NH 2 ) composites with diverse acid-base properties. Results show that all the obtained composites exhibited a satisfactory CO 2 adsorbing capacity (33–54 cm 3 /g) and delivered a remarkable yield of target cyclic carbonate at either mild thermal conditions (0.1 MPa CO 2 and 80 o C) or under light irradiation (light intensity: ~350 mW/cm 2 ) at room temperature. Even with diluted CO 2 (15 vol. % CO 2 ), high yields of 80–82 % are achievable. Moreover, the used catalysts can be easily recycled from reaction systems, leading to a good recyclability .
研究领域:
材料科学
·
催化化学
·
环境科学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF HAZARDOUS MATERIALS
·
2022
·
IF 14.224
Zhen Huang,Chao Xiong,Lingri Ying,Welong Wang,Shixing Wang,Jing Ding,Jianfeng Lu
Lead ions in water have notorious effects on humans and environment. It is important to design an adsorbent with high adsorption capacity and reproducibility for efficiently removing Pb (II)ions from polluted water. Here, a novel Ti-based MOFs material (BDB-MIL-125(Ti)@Fe 3 O 4 ) was prepared by modifying NH 2 -MIL-125(Ti) with sulfhydryl and amino groups. Due to the large number of active sites, the maximum Pb (II) adsorption capacity of BDB-MIL-125(Ti)@Fe 3 O 4 was 710.79 mg/g at 25 °C and pH = 6 within 120 min corresponding to a maximum removal rate of 95.68%. The adsorbent also has extremely high selectivity and good cycling adsorption performance. The adsorption isotherms and kinetics agree with the Langmuir and the pseudo-second-order models, indicating that the process was chemisorption . Thermodynamic studies prove that spontaneous processes enhance Pb (II) adsorption at higher temperatures. DFT and FMOs calculations were used to discuss the adsorption mechanism. The sulfhydryl groups on the surface of organic ligands have a stronger affinity for Pb (II).
研究领域:
环境科学
·
材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
APPLIED SURFACE SCIENCE
·
2022
·
IF 7.392
Weiwei Li,Wenlan Ji,Murat Yılmaz,Tian C. Zhang,Shaojun Yuan
Arsenic is a toxic carcinogen, and arsenic pollution in groundwater is one of the most serious environmental problems in the world. Thus, it is an urgent problem to efficient removal of arsenic from groundwater. In this work, a novel MWCNTs/MIL-53(Fe) nanocomposite was successfully synthesized to improve the water stability of MIL-53(Fe) by incorporation of carboxylated multi-walled carbon nanotubes (MWCNTs) using a one-pot hydrothermal method, and was then used to efficiently adsorb As(V) ions from groundwater. Adsorption experimental results demonstrated an ultrafast adsorption rate of As(V) on the MWCNTs/MIL-53(Fe) nanocomposites in solution pH values of 3 to 10, and the adsorption equilibrium could be reached in circa 20 min with an adsorption capacity of 27.24 mg·g −1 in a low As(V) concentration of 10 mg·L −1 . The adsorption kinetics of As(V) on the MWCNTs/MIL-53(Fe) was found in line with the pseudo-second-order (PSO) kinetic model, and was simultaneously controlled by both internal diffusion and liquid film diffusion. The adsorption isotherm data conformed to the Redlich-Peterson isotherm model, indicating both physical and chemical adsorption occurred at heterogeneous interfaces. Moreover, the postulated adsorption mechanism of As(V) on MWCNTs/MIL-53(Fe) nanocomposites was ascribed to hydrogen-bond interaction, electrostatic attraction and chemical complexation. Therefore, the as-prepared MWCNTs/MIL-53(Fe) nanocomposites not only exhibit superior water stability and outstanding adsorption performance in removing arsenic-contaminated groundwater, but also offer a novel insight for rational preparation of water-stable MOF-based composites.
研究领域:
环境科学
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
·
2024
·
IF 5.8
Ziyang Zhang,Haoshuo Li,Jianguo Yuan,Shouwu Yu,Shujuan Xiao
The catalyst loading onto polymer films by pump-filtration can effectively solve the problem of catalyst separation and recycling, as well as expose more catalytically active sites. However, this method suffers from the disadvantage of poor catalyst attachment stability, which reduces the ability to catalyze the degradation of pollutants. In this paper, the high adhesion and film-forming properties of chitosan (CS) were utilized to modify the ZnO/NH 2 -MIL-88B (ZM) catalyst-loaded polypropylene non-woven (PP) composite membranes obtained by filtration, and CS/[ZM@PP] catalytic membranes with excellent catalyst adhesion stability and catalytic degradation performance were prepared. The results showed that the prepared CS/[ZM@PP]-X catalytic membranes significantly improved the recovery of the catalysts and possessed good catalytic performance, and the best-performed CS/[ZM@PP]-3 membrane could degrade more than 96.8 % of methylene blue (100 mL, 20 mg/L) within 60 min. In this paper, the effects of different factors on the catalyst recovery on the catalytic membrane were systematically investigated, and the prepared CS/[ZM@PP]-3 membrane can adapt to the complex aqueous environment, has excellent cycling stability, and still has more than 90 % degradation effect after 6 times of recycling, which has good potential for practical application.
研究领域:
环境科学
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY
·
2023
·
IF 2.2
Shanghai Dong,Liying Wang,Weiyi Lou,Yunxin Shi,Lu Li,Zhenzhu Cao,Yongfeng Zhang,Junmin Sun
Nowadays, more and more regions of the earth are facing energy crisis and environmental pollution issues. Photocatalytic technology converts solar energy into chemical energy in an environmentally friendly way, which is considered as an effective method to solve such issues. In this work, a series of TiO2/Bi-MOFs (TiO2/Bismuth based metal-organic frameworks) composites were successfully prepared by a simple one-pot solvothermal method, and the photocatalytic activity of the composites was evaluated by photocatalytic degradation of rhodamine B (RhB) dye under visible light, and the catalytic activities of the samples were also investigated for methyl orange (MO), methylene blue (MB) and tetracycline (TC). The samples were characterized by using various analytical techniques. The composites exhibited better catalytic properties compared with the original single component, which was attributed to the high dispersion of TiO2 and the synergistic effect of efficient interfacial charge transfer between TiO2 and Bi-BTC (BTC: benzene-1,3,5-tricarboxylate, Scheme 1). Among the results, the photocatalytic degradation efficiencies of 25-T/B (T/B, TiO2/Bi-BTC: TiO2/bismuth homobenzotrizoate composites), 35-T/D (T/D, TiO2/Bi-BDC: TiO2/bismuth terephthalate composites) and 25-T/P (T/P, TiO2/Bi-BPDC: TiO2/bismuth biphenyldicarboxylate composites) for RhB were all 99% after 40 min of visible light irradiation. Furthermore, the degradation efficiency of 25-T/B for RhB could maintain high catalytic activity after five cycles, indicating the high stability of the catalyst. Overall, the materials presented in this work are a series of reusable, high catalytic activity and economical photocatalysts for water purification, and the effects of different ligands on the photocatalytic activity of TiO2/Bi-MOFs composites were investigated.
研究领域:
材料科学
·
环境科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
·
2023
·
IF 2.5
Liu Wenjun,Guan Jinyu,Kong Bo,Lu Hongbing,Wu Yu,Qin XiaoLi,Jiang Hongmei,Liu Xiaoying
The severe toxicity of heavy metal ions (HMIs) to both the environment safety and human health makes it challenging to build a system that can simultaneously detect them. A method simultaneous electrochemical detection of Cd 2+ and Pb 2+ was developed here using amino-functionalized bismuth-based metal–organic frameworks (NH 2 -Bi-MOFs) and graphene aerogels (GAs) composites. The GAs/NH 2 -Bi-MOFs composites were made by ultrasonically depositing the NH 2 -Bi-MOF on the GAs. GAs support NH 2 -Bi-MOFs and boost their conductivity by accelerating electron transmission through the matrix. NH 2 -Bi-MOFs acted as a binding site for Cd 2+ and Pb 2+ , because hydrophilic groups (-NH 2 ) and bismuth metal active sites collaborated. The GAs/NH 2 -Bi-MOFs composite–modified electrodes detection capability was assessed. The proposed electrochemical sensor can be effectively used for individual and simultaneous detection of the Cd 2+ and Pb 2+ in aqueous solutions with outstanding sensitivity and interference used to simultaneously detect Cd 2+ and Pb 2+ in river water and tap water samples with satisfactory accuracy and repeatability. This paper provides a unique technique for concurrently detecting Cd 2+ and Pb 2+ in practical applications.
研究领域:
环境科学
·
材料科学
·
分析化学
·
电化学
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）