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Structural Optimization of PA12/MVQ@POE-g-MAH Ternary Composite for Superior Toughness and Low-Temperature Resistance

Zeshang Jiang,Zhongtian Li,Jieting Geng,Lin Xia

To enhance the low-temperature toughness and resistance of the engineering plastic polyamide PA12, this study introduces novel PA12/MVQ@POE- g -MAH ternary composites using a two-step process and dynamic curing. Analytical results indicate that incorporating MVQ@POE- g -MAH into the PA12 matrix markedly enhances its toughness and heat resistance. As the MVQ@POE-g-MAH content increases, the elongation at break of PA12 composites significantly expands from 52.83% to 204.69%, and the notch impact strength escalates from 8.69 to 74.34 kJ m −2 . In addition, the brittleness temperature of PA12 decreases from −59.5 to −67.0 °C. Experimental findings confirm that POE- g -MAH is dispersed at the interface between MVQ and PA12, creating an encapsulated structure of MVQ@POE- g -MAH. This enhancement significantly broadens the potential applications of PA12 by improving its toughness, and resistance to both low and high temperatures, as well as impact endurance.