ANALYST
·
2023
·Vol. 148
·期 8
·1838-1847
·
IF 4.2
Zhidong Zhao,Yuan He,Xingrui Qi,Nian Li,Zijian He,Yufang Chen,Tao Jin
Electrochemical determination of synthetic opioids such as fentanyl is meaningful but still challenging no matter from a social or academic perspective. Herein, we report a series of novel electrocatalysts based on Fe-containing metal–organic frameworks and multi-walled carbon nanotubes (Fe-MOF/MWCNTs). The obtained Fe-MOF/MWCNT electrode materials all show ultrasensitivity on fentanyl determination. In particular, MOF-235/MWCNTs even exhibit an ultra-low limit of detection (LOD) of 0.03 μM with a wide linear range from 0.1 to 50 μM. Besides, this series of Fe-MOF/MWCNTs also displays excellent repeatability, selectivity, and stability. Moreover, they show good performance in real sample detection and achieve good recovery of 95.47%–102.41% and 96.62%–103.15% in blood and urine samples, respectively. This high performance in fentanyl determination is mainly contributed by the Fenton-like process and the adsorption function of the Fe-MOF. Therefore, these novel Fe-MOF/MWCNTs are promising electrocatalysts for point-of-care device fabrication and also have potential applications in fentanyl rapid test technology.
研究领域:
分析化学
·
材料科学
·
毒理学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Materials Today Nano
·
2025
·
IF 8.2
Teng Zhou,Daohai Zhang,Kunlan Diao,Jiajia Du,Yupeng Hu,Zhi Lei,Dongju Liu,Shan Liu,Shuhao Qin
With the widespread popularity of digital technology, electromagnetic interference(EMI) has become a new type of pollution that endangers electronic equipment and biological systems. In this paper, MWCNTs@TiO 2 composite materials were prepared by the hydrothermal synthesis method and then added into the three dimensional framework constructed by PAM (polyacrylamide) and PEG (polyethylene glycol) to obtain hydrogels with EMI functionality. It was found that in the M@T/PAM-4 (MWCNTs@TiO 2 /PAM-4) hydrogel, due to the fact that TiO 2 particles were loaded on the surface of MWCNTs, its cross section presented a granular shape. As the content of MWCNTs increased, the EMI SE T of the hydrogel increased, with the M@T/PAM-4 hydrogel reaching 29 dB. The electrical conductivity and mechanical properties also increased accordingly. Compared with the pure PAM hydrogel, they were respectively improved by 626 % and 24.5 %, which was attributed to the formation of a conductive network by MWCNTs and the enhancement of interfacial polarization, etc. Meanwhile, the water retention rate of the M@T/PAM-4 hydrogel could still reach 34.1 % after 8 h. Moreover, it also had a relatively high water content of 69.08 %. Therefore, This improves the application value and development prospects of the hydrogel in fields such as Electromagnetic (EM) shielding.
研究领域:
材料科学
·
环境科学
·
电子工程
✓ 已验证
产品关联
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2014
·
IF 4.058
Lixin Zhou,Shengdong Pan,Xiaohong Chen,Yonggang Zhao,Baobo Zou,Micong Jin
A novel core–shell covalently functionalized Fe 3 O 4 coated SiO 2 decorated multi-walled carbon nanotubes (Fe 3 O 4 @SiO 2 –MWCNTs) adsorbent was synthesized and characterized by scanning electron microscopy, transmission electron microscopy, Fourier Transform Infrared Spectrum (FTIR), Thermogravimetry, X-ray diffraction and magnetic measurements. The pentachlorophenol (PCP) adsorption effect factors of initial concentration, contact time, solution pH and temperature were investigated in detail. It was found the absorption capacity was strongly depended on pH, and the maximum adsorption value for PCP (96.4 mg/g) was obtained at pH 2.5. The equilibrium was attained within 30 min, and the adsorption kinetics was better described by pseudo-second-order kinetic model. The data pointed out excellent fit to Freundlich isotherm model. Thermodynamic parameters such as standard enthalpy (Δ H θ ), standard entropy (Δ S θ ) and standard free energy (Δ G θ ) showed that the adsorption of PCP onto Fe 3 O 4 @SiO 2 –MWCNTs was spontaneous, endothermic and random within the temperature range of 288–318 K. The results indicate that the Fe 3 O 4 @SiO 2 –MWCNTs adsorbent is a potential low-cost effective material for PCP removal from contaminated wastewater.
研究领域:
环境科学
·
材料科学
✓ 已验证
DOI
高影响因子
Journal of Environmental Chemical Engineering
·
2025
·
IF 7.2
Haonan Guo,Bingzhu Wang,Pengcheng Hu,Haiwang Wang
The photocatalytic material CdS has the advantages of a narrow energy gap and a suitable conduction band potential, but the rapid compounding of photogenerated carriers limits its large-scale application. To overcome these drawbacks, MWCNTs-CdS composites were prepared in this work and the thermodynamic and kinetic behaviour during the hydrothermal growth of MWCNTs-CdS was investigated. On this basis, the microscopic morphology of MWCNTs-CdS was regulated by designing the ratio of oleic acid and oleylamine, which in turn improved the photocatalytic hydrogen production efficiency of MWCNTs-CdS. The results showed that MWCNTs effectively improved the photogenerated carrier utilisation efficiency of CdS, and with the prolongation of hydrothermal time and the increase of temperature, the crystallinity of CdS increased and the photogenerated electron-hole complexation rate decreased. In addition, the introduction of oleic acid and oleylamine led to a decrease in the particle size and an increase in the specific surface area of MWCNTs-CdS, which in turn enhanced the photocatalytic performance. Under the light condition, the hydrogen production rate of MWCNTs-CdS(OAc:OAm=0.5:1.5) reached 189.10 μmol/g/h, which was 13.30 times higher than that of pure CdS.
研究领域:
材料科学
·
化学工程
·
环境科学
✓ 已验证
产品关联
DOI
高影响因子
Analytical Methods
·
2024
·
IF 2.7
Weiqiang Li,Xiaoxue Liu,Pianpian He,Wentao Hu,Kaijie Tang,Yangping Wen,Qian Zeng,Huiyi Tang,Yaxuan Lei,Xin Liu
Deoxynivalenol (DON) has drawn considerable attention for its obvious pathogenicity and wide use in agro-products, which cause a potential threat to human health. In this work, an electrochemical immunosensor is developed for the highly sensitive and selective detection of DON in wheat flour using AuNPs-BP-MWCNTs-COOH and antibodies. The AuNPs-BP-MWCNTs-COOH nanocomposite was prepared via an in situ reduction reaction and ultrasonic-assisted liquid-phase exfoliation. The nanocomposite exhibits a larger surface area, decent stability, excellent electron transfer capability, good protein binding capability and prominent specificity. The plentiful carboxyl group on the nanocomposite can bind to the amino group of the antibody, and AuNPs have an affinity for the sulfhydryl group of the antibody, which makes it feasible for the nanocomposite to load the antibody. The peak currents are plotted against the logarithm of DON concentration from 0.002 to 80 ng mL−1 with a limit of detection (LOD) of 0.5 pg mL−1. This approach establishes an effective label-free immunosensor platform for the detection of DON with high sensitivity and selectivity in various food and agricultural products.
研究领域:
食品安全
·
分析化学
·
纳米技术
✓ 已验证
产品关联
DOI
PubMed
高影响因子
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
·
2021
·
IF 4.539
Qipeng Yang,Ru Song,Yameng Wang,Xianlong Hu,Zhiyue Chen,Zhuo Li,Weiqiang Tan
A new electrode material consisting of MOFs (Zr-TAA, TAA: trans-aconitic acid) and MWCNTs was simply synthesized by one-pot reflux method and applied to high-performance supercapacitor. With advantages of improved conductivity and uniform pore-size distribution, the composite material shows enhanced electrochemical performance with a specific capacitance of 562.06 F g −1 and retains almost 100% of its initial capacitance after 1000 cycles when measured in 6 M KOH electrolyte. Furthermore, an asymmetric supercapacitor assembled by Zr-TAA/MWCNTs-6 as positive electrode and carbon cloth as negative electrode exhibits a superior energy density of 17.53 Wh kg −1 at a power density of 902.5 W kg −1 , which demonstrates its great practical value in electrochemical energy storage applications.
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
高影响因子
Analytical Methods
·
2025
·
IF 2.6
Wei Liu,Honghuang Li,Deming Li,Xiaoting Liu,Lei Liu,Zhiyong Zhu,Haoyu Hao,Qiongyao Zeng,Yanhua Sun
In this work, MWCNTs/Ti3C2 nanocomposites have been synthesized by a convenient method and characterized in terms of structure and properties by SEM, FT-IR, XPS and electrochemical methods. The electrochemical sensor developed by MWCNTs/Ti3C2 nanocomposites has good electrochemical properties. The sensor has good electrocatalytic performance for H2O2 and was used to detect the concentration of H2O2. The sublinear range of detection was 0.05-1080 μM and the detection limit was 0.017 μM (S/N=3). The sensor has strong anti-interference performance, stability and reproducibility, and has shown good performance in real sample detection.
研究领域:
材料科学
·
分析化学
·
生物医学工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子
RSC Advances
·
2015
·Vol. 5
·期 59
·47820-47829
·
IF 3.84
Ziyang Lu,Ming He,Lili Yang,Zhongfei Ma,Li Yang,Dandan Wang,Yongsheng Yan,Weidong Shi,Yang Liu,Zhoufa Hua
A novel imprinted CoFe2O4/MWCNTs photocatalyst was prepared through the combination of a hydrothermal method and suspension polymerization based on 2-mercaptobenzothiazole (MBT) as the molecular template, pyrrole as the imprinted functional monomer and conductive polymerizable monomer, and CoFe2O4/MWCNTs as the matrix material. The results indicated that the surface imprinted layer was successfully coated on the surface of CoFe2O4/MWCNTs and polypyrrole (PPy) was formed and existed in the surface imprinted layer, the magnetic saturation value of the novel imprinted CoFe2O4/MWCNTs photocatalyst was 19 emu g−1. Moreover, compared with other photocatalysts, the novel imprinted CoFe2O4/MWCNTs photocatalyst not only had a high photocatalytic efficiency (57.09%), but also possessed a strong ability for selective recognition and photodegradation of MBT (the coefficients of selectivity of the novel imprinted CoFe2O4/MWCNTs photocatalyst relative to CoFe2O4/MWCNTs and the non-imprinted CoFe2O4/MWCNTs photocatalyst was 3.37 and 3.28, respectively). In addition, in the process of the photodegradation reaction, h+ and ˙OH were the main oxidative species, ˙O2− played a very small role.
研究领域:
材料科学
·
环境科学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF CHEMICAL PHYSICS
·
2024
·Vol. 160
·期 20
·
IF 3.1
Li Qingxia,Song Dongmei,Zhan Xinxing,Tong Xin,Hu Changgang,Tian Juan
Zeolitic Imidazolate Frameworks-8 (ZIF-8) is commonly used as an ideal precursor for non-noble metal catalysts because of its high specific surface area, ultra-high porosity, and N-rich content. Upon pyrolyzing ZIF-8 at 900 °C in Ar, the resulting material, referred to as Z 8 , displayed good activity toward the oxygen reduction reaction (ORR). Then the ZIF-8 was mixed with various conductive carbon materials, such as multiwall carbon nanotubes (MWCNTs), Acetylene black (ACET), Vulcan XC-72R (XC-72R), and Ketjenblack EC-600JD (EC-600JD), to form Z 8 composites. The Z 8 /MWCNTs composite exhibited enhanced ORR activity owing to its network structure, meso-/microporous hierarchical porous structure, improved electrical conductivity, and graphitization. Subsequently, iron and nitrogen co-doping is achieved through the pyrolysis of a mixture comprising Fe, N precursor, and ZIF-8/MWCNTs, which is denoted as FeN-Z 8 /MWCNTs. The intrinsically high electrical conductivity of MWCNTs facilitated efficient electron transfer during the ORR, while the meso-/microporous hierarchical porous structure and network structure of Fe, N co-doped ZIF-8/MWCNTs promoted oxygen transport. The presence of Fe-containing species in the catalyst acted as activity centers for ORR. This strategy of preparing Z 8 composites and modifying them with Fe, N co-doping offers an insightful approach to designing cost-effective electrocatalysts.
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Materials Today Communications
·
2025
·
IF 4.5
Zhanpeng Yu,Xin Sun,Cong Qi,Maoqing Tang,Cheng Xue
In order to enhance solar evaporation efficiency and reduce cost, the study combined polyvinylidene fluoride (PVDF) and multi-walled carbon nanotubes (MWCNTs) with low-cost cotton fabrics. The PVDF@MWCNTs cotton composite films were prepared by non-solvent induced phase separation method, which demonstrates excellent photothermal conversion performance. The effects of structure (two-dimensional structure, three-dimensional structure), shape of three-dimensional evaporation structure (triangular, semicircular and rectangular), light intensity and brine concentration on the evaporation performance were experimentally investigated. The evaporation rate of the rectangular structure with a height of 15 mm is 3.083 kg/m 2 ·h and the evaporation efficiency is 0.938 under two light intensities and a seawater concentration of 4 wt%. The evaporation rate of the two-dimensional structure for the same material is basically in the range of 1.50 kg/m 2 ·h. The evaporation rate can be more than doubled in three-dimensional structures compared to two-dimensional structures.
研究领域:
材料科学
·
能源与环境科学
✓ 已验证
产品关联
DOI
高影响因子
MICROCHEMICAL JOURNAL
·
2020
·
IF 3.594
Aijuan Xie,Haoye Wang,Jiajun Zhu,Jianing Chang,Linyang Gu,Chenyang Liu,Yun Yang,Yihan Ren,Shiping Luo
CuZnO x /Multi-walled carbon nanotubes (MWCNTs) were synthesized by coprecipitation method, which was used as electrochemical sensor to detect the response of caffeic acid (CA). The morphology and elemental composition of as-prepared materials were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS). Electrochemical performances of materials were investigated through cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), and the content of CA was determined by differential pulse voltammetry (DPV). The CV results proved that the optimal CuZnO x /MWCNTs modified GCE had a lower limit of detection of 0.155 μM (LOD = 3Sb/S) with a wide linear range of 1–100 μM, good reproducibility, repeatability and stability for CA detection. The CuZnO x /MWCNTs sensor can be used to detect CA in coffee and white wine. The findings could contribute to the development of new high-performance sensors for monitoring diet and food safety.
研究领域:
分析化学
·
食品安全检测
✓ 已验证
产品关联
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2025
·
IF 13.2
Yutian Cai,Runyang Zhou,Shanshan Zhang,Mengke Qiao,Yongzhi Cheng,Yingli Zhu,Hui Luo,Pingan Chen,Xiangcheng Li,Fu Chen
MOFs-derived magnetic carbon-based composites exhibit great application potentials in electromagnetic absorption field. Nowadays, the MOF-on-MOF hybrid materials, constructed by self-assembly of two or more MOFs, gradually become the prevailing precursors for efficient microwave absorbers due to the flexible structure and component design which are beneficial to improving microwave attenuation and optimizing impedance matching. Herein, the binary MOF-on-MOF hybrid templates MIL-88A@ZIF-67 has been fabricated based on a surfactant-assisted growth strategy, and subsequently thermally converted into the spindle-like Co 3 Fe 7 @NC/magnetic MWCNTs composites (CFM) through a DCDA-assisted carbothermal reduction method. It has been revealed that the carbothermal temperature could not only regulate the crystallinity of Co 3 Fe 7 alloys and magnetism of CFM composites, but also make significant impact on chemical and mesoscopic structure of conductively hierarchical architecture composed by surficial MWCNTs and pyrolytic carbon derived from various ligands of different MOFs. Among the three proposed absorbers in this work, the CFM-700 sample with densest surficial magnetic MWCNTs achieved a satisfied balance between intrinsic microwave consumption and impedance matching due to the magnetic-dielectric synergistic effect. The reflection loss of CFM-700 could keep staying below −20 dB in an ultra-wide range from 3.6 GHz to 18.0 GHz when the thickness varies from 1.3 mm to 5.45 mm. Moreover, the minimum reflection loss of CFM-700 is −68.75 dB at 1.88 mm and the effective absorbing bandwidth could reach 4.72 GHz at only 1.55 mm. It is believed that this work paves an inspiring way to design conductively hierarchical magnetic carbon-based composites with excellent microwave absorption through construction of MOF-on-MOF hybrid structures.
研究领域:
材料科学
·
电磁学
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）