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Vanadium Oxide Pillared by Interlayer Mg2+ Ions and Water as Ultralong-Life Cathodes for Magnesium-Ion Batteries

Yanan Xu,Xuanwei Deng,Qidong Li,Guobin Zhang,Fangyu Xiong,Shuangshuang Tan,Qiulong Wei,Jun Lu,Jiantao Li,Qinyou An,Liqiang Mai

Magnesium-ion batteries (MIBs) show great potential for large-scale energy storage because of the advantages of low cost and safety, but their application is severely hindered by the difficulty in finding desirable electrode materials. Herein, we develop a bilayer-structured vanadium oxide (Mg 0.3 V 2 O 5 ·1.1H 2 O) with synergistic effect of Mg 2+ ions and lattice water as the cathode material for MIBs. The pre-intercalated Mg 2+ ions provide high electronic conductivity and excellent structural stability. The lattice water enables fast Mg 2+ ions mobility because of its charge shielding effect. As a result, the Mg 0.3 V 2 O 5 ·1.1H 2 O exhibits excellent rate performance and an unprecedented cycling life with capacity retention of 80.0% after 10,000 cycles. In addition, the Mg 0.3 V 2 O 5 ·1.1H 2 O exhibits good electrochemical performance in full MIBs. This scalable Mg 2+ host material is a promising candidate as a cathode for MIBs, and its high performance is expected to meet the requirements for large-scale storage applications.