Laser & Photonics Reviews
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2024
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IF 9.8
Ting Gong,Yang Yang,Tongtong Xuan,Wenhao Bai,Haorui Dong,Tianliang Zhou,Rong-Jun Xie
Quantum dot (QD) color conversion films (QD-CCFs) are used in ultrahigh definition (UHD) Mini-LED backlit displays due to their narrow band emission and high color purity. However, their poor light conversion efficiency (LCE) leads to greater film thickness and thus high cost. Herein, this study proposes a local light field control strategy to enhance the LCE of QD-CCFs using high-refractive BN nanosheets. The LCEs of the green and red QD-CCFs can increase from 29.9% and 34.8% to 67.4% and 91.0% after adding BN nanosheets, respectively. Combining the experimental data with the finite-difference time domain (FDTD) simulations, the enhanced LCEs can be attributed to observably increased blue light absorption and improved light extraction efficiency of the light emitted from QDs. The white Mini-LEDs, prepared by integrating the optimized QD-CCFs containing BN nanosheets with blue Mini-LED chips, show a high luminous efficiency of 70.2 lm W −1 , a high external quantum efficiency of 36.2%, and a wide color gamut of 96.3% Rec . 2020 standards. This work provides an interesting idea for designing high-efficiency QD-CCFs toward low-cost UHD Mini-LED backlit displays.
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光学材料
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高影响因子
ACS Applied Materials & Interfaces
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2023
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IF 9.5
Haorui Dong,Haiyan Zhao,Tongtong Xuan,Wenhao Bai,Tianyu Lin,Yixin Cai,Rong-Jun Xie
Lead halide perovskite nanocrystals (NCs) have been the star material in lighting and displays owing to their excellent photoelectrical properties, but they have not simultaneously realized high photoluminescence quantum yield (PLQY) and high stability. To solve this problem, we propose a perovskite/linear low-density polyethylene (perovskite/LLDPE) core/shell NC by the synergistic role of the pressure effect and steric effect. Green CsPbBr3/LLDPE core/shell NCs with near-unity PLQY and nonblinking behavior were synthesized through an in situ hot-injection process. The mechanism of the improved photoluminescence (PL) properties is the enhanced pressure effect resulting in increased radiative recombination and interaction between the ligand and perovskite crystals, as confirmed by the PL spectra and finite element calculations. Meanwhile, the NCs show high stability under ambient conditions (with a PLQY of 92.5% after 166 days) and against 365 nm UV light (maintaining 61.74% of the initial PL intensity after continuous radiation for 1000 min). This strategy also works well in the blue and red perovskite/LLDPE NCs and red InP/ZnSeS/ZnS/LLDPE NCs. Finally, white-emitting Mini-LEDs were fabricated by combining the green CsPbBr3/LLDPE and red CsPbBr1.2I1.8/LLDPE core/shell NCs with blue Mini-LED chips. The white-emitting Mini-LEDs exhibit super wide color gamut (∼129% of the National Television Standards Committee or 97% of the Rec. 2020 standards).
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材料科学
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光学工程
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PubMed
高影响因子
Nano Energy
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2022
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IF 19.069
Tongtong Xuan,Shaoqiang Guo,Wenhao Bai,Tianliang Zhou,Le Wang,Rong-Jun Xie
Although tremendous efforts have been made to enhance the stability of lead halide perovskite quantum dots (PeQDs), they cannot meet the long-term requirements of photoelectric devices due to their poor reliability when attacked by multiple factors. Herein, we report ultrastable CsPbBr 3 :Sr/PbBr(OH)/molecular sieve composites with a high photoluminescence quantum yield of 75% and high overall stability when exposed to water, blue light and heat, owing to (i) the increased formation energy of CsPbBr 3 PeQDs by Sr doping and (ii) good encapsulation by PbBr(OH) and molecular sieves. These composites maintain 54% of their initial intensity after being aged at 85 °C and 150 mW cm −2 for 720 min, which is superior to commercial green CdSe-based QDs. These promising composites are then used to produce Mini-LED backlights with a high luminous efficacy of 86 lm/W and a color area of ~124% of the National Television Standards Committee or 93% of the Rec. 2020 standards by combining them with red CdSe/CdS/ZnS QDs and a blue Mini-LED chip. We believe that highly reliable PeQDs can be achieved by building well-designed composite structures, thus enabling them to be practically applied in emerging lighting and displays.
研究领域:
材料科学
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光电技术
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高影响因子
CERAMICS INTERNATIONAL
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2023
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IF 5.2
Hongxing Xie,Qizhong Lin,Xinyuan Chen,Sijin Liu,Xingke Zheng,Aochen Du,Zhenyu Zeng,Tianyong Guan,Yun Ye,Enguo Chen,Sheng Xu,Yang Li,Tailiang Guo
Quantum dots (QDs) have showed great potential for next-generation lighting and display technologies. However, its stability is still one of the key problems that limit its practical application. In this paper, by comparing the specific surface area (SSA) and pore width of aluminum oxide (AlO x ) and silicon oxide (SiO 2 ) barrier layers, the relationship between the porosity of barrier layers and the stability of QDs was studied. The results showed that the synthesized SiO 2 -QD-AlO x , which has the smallest SSA in the synthesized QD composites, exhibited the best stability on the quantum dot diffuser plate (QD-DP). Moreover, the operational lifetime (T 80 ) at 450 nm blue light excitation was increased by a factor of 3.41 compared to that of bare QDs. Meanwhile, the prepared QD-DP containing dense SiO 2 -QD-AlO x composites significantly improved the resistance to light, heat, moisture and oxygen. Finally, the prepared QD-DP was assembled into a Mini-LED TV with a wide color gamut and excellent display performance (a color gamut of 157.4 % for commercial normal TV, and 107.19 % for the National Television System Committee (NTSC 1931)). This technique provides favorable guide for effectively enhancing the stability of QDs in lighting and display technologies.
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材料科学
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高影响因子
CHEMICAL ENGINEERING JOURNAL
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2023
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IF 15.1
Kun He,Dejian Chen,Linfeng Yuan,Jiamin Xu,Kunyuan Xu,Jie Hu,Sisi Liang,Haomiao Zhu
The polymeric composite films incorporating inorganic lead halide perovskite quantum dots (CsPbX 3 QDs, X = Cl, Br or I) are promising color conversion layers for wide gamut display devices such as Mini-LED backlight-based televisions. However, the relatively low emission efficiency and poor stability of these composite films present significant challenges for practical applications. In this study, we present a novel low-temperature in-situ crystallization strategy to prepare CsPbBr 3 /PVDF composite film through a rational designed of precursor, solvent and polymer structure. The strong interaction between PVDF and perovskite QDs via Lewis acid-base interaction allows for precise control over the crystallization and passivation of perovskite QDs. The optimized CsPbBr 3 /PVDF film exhibits bright emission with a photoluminescence quantum yield (PLQY) of up to 70 %, surpassing those of other CsPbBr 3 /polymers counterparts. Furthermore, the films demonstrate remarkable stability, retaining over 90 % of their original PLQY even after 50 days of aging under various environmental conditions such as exposure to air, immersion in water and blue light irradiation. By integrating the green and red emissive CsPbX 3 /PVDF films with blue Mini-LEDs, we successfully fabricate a prototype liquid crystal display (LCD) with an outstanding wide color gamut (128 % of NTSC 1931). These performances outperform that of commercial white-LED-based LCDs, highlighting the immense potential of CsPbX 3 /PVDF for high-definition display applications in the future.
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材料科学
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高影响因子
Journal of Materials Chemistry C
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2023
·Vol. 11
·期 28
·9486-9494
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IF 6.4
Yixin Cai,Yang Yang,Haorui Dong,Tongtong Xuan,Xueyuan Tang,Rong-Jun Xie
Pure red mixed halide CsPbBr3−xIx perovskite nanocrystals (NCs) exhibit a high photoluminescence quantum yield (PLQY) and narrow full width at half maximum (FWHM), but there are phase stability issues that hinder their application in displays. In this work, we propose pure red CsPbBr0.96I2.04/SiO2 core/shell NCs by using (3-aminopropyl)triethoxysilane as the surface ligand and silicon source via a hot-injection and in situ hydrolytic process. The CsPbBr0.96I2.04/SiO2 NCs not only show excellent optical properties with a near-unity PLQY but also exhibit high stability against moisture, blue light, and heat. Pure red CsPbBr0.96I2.04/SiO2 NC inks were prepared by dispersing CsPbBr0.96I2.04/SiO2 NCs into a mixed solvent of toluene and dodecane and used to inkjet print NC color conversion films (NC-CCFs) with excellent luminescence uniformity and high stability. Finally, white-emitting Mini-LEDs were fabricated by combining pure red CsPbBr0.96I2.04/SiO2 NC-CCFs with green CsPbBr3/SiO2 NC-CCFs and blue Mini-LED chips, showing a high external quantum efficiency (EQE) of 24.8% and an ultrawide color gamut of 132.58% NTSC and 99.2% Rec. 2020 standards. This demonstrates the potential of pure red CsPbBr0.96I2.04/SiO2 NCs for Mini-LED backlights.
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材料科学
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光电技术
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纳米技术
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高影响因子
危险品化学品经营许可证（带存储）