Development of a compact MnO2 filter for removal of SO2 from diesel vehicle emissions
Increasing concern about sulfur dioxide (SO2) from diesel vehicle exhausts causing detrimental effects on NOx removal catalysts has resulted in the development of dry desulfurization filters for complete removal of SO2. In this study, a compact MnO2 filter was developed for diesel emission control. The SO2-capture behavior of the compact MnO2 filter was investigated by using a volumetric device in a low temperature range (200–400 °C) and low SO2 pressure conditions. The maximal capacity of the MnO2 filter was 304.1 mgSO2 per gMnO2 at 400 °C. Based on the experimental results, the required volume of the MnO2 filter was estimated as only 0.6 L for a diesel car with 30 000 km distance traveled per year. The thickness of the MnO2 filter had significant influence on its SO2-capture performance. The sulfate reaction mechanism was also discussed by using a grain model under four reaction temperature conditions for improving the efficiency of the design of the desulfurization filter. The sulfate process can be divided into two control stages (the chemical reaction control stage and the solid diffusion control stage) and the prediction models fit the experimental data well for both control stages, indicating that the two-stage grain model is suitable for the sulfate reaction between the MnO2 filter and SO2. The calculated apparent activation energy of 18.8 kJ mol−1 indicates that the MnO2 filter exhibits high activity for SO2 adsorption in a pure SO2 atmosphere.
危险品化学品经营许可证（带存储）