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Metallic Ni Promoted Mo2C-MoN Particles Supported on N-Doped Graphitic Carbon as Bifunctional Catalyst for Oxygen and Hydrogen Evolution Reaction in Alkaline Media

Yunfeng Zhan,Fangyan Xie,Hao Zhang,Zhipeng Lin,Jilin Huang,Weihong Zhang,Xueliang Sun,Hui Meng,Yueli Zhang,Jian Chen

A highly active and stable bifunctional electrocatalyst for oxygen evolution reaction (OER) and hydrogen evolutionreaction (HER) in alkaline media based on Ni-doped Mo2C-MoN particles supported on porous N-doped graphitic carbon is studied in this work. The optimized Mo2C-MoN/Ni@NC catalyst shows small over potential of 296 mV and 183 mV at 10 mA cm−2 on glassy carbon electrode for OER and HER, respectively. The best catalyst is the mixture of hexagonal Mo2C, MoN and metallic Ni. The high catalytic performance is explained by the synergistic effect between metallic Ni and Mo compounds. The promotion effect of Ni to Mo2C-MoN leads to high OER activity and Mo2C is crucial for HER. The good stability and easily scale-up make the Mo2C-MoN/Ni@NC a promising bifunctional catalyst for water splitting in alkaline media.