ACS Applied Materials & Interfaces
·
2022
·
IF 10.383
Yating Fang,Yue Jiang,Zhengchi Yang,Zhengjie Xu,Zhen Wang,Xubing Lu,Xingsen Gao,Guofu Zhou,Jun-Ming Liu,Jinwei Gao
With the steady industrialization process of the perovskite solar cells (PSCs), the toxicity of the used solvents has become a pivotal issue that needs to be addressed. Especially, the usage of N,N-dimethylformamide (DMF) solvent would pose serious environmental and health concerns. Herein, we have reported a nontoxic solvent N-formylmorpholine (NFM) to replace the toxic DMF and have achieved a higher PCE of 22.78% compared to 21.97% when DMF was adopted. Moreover, with NFM, a widened antisolvent processing window was observed, facilitating the fabrication of PSCs with high reproducibility. This solvent engineering strategy offers an important solution to prepare eco-friendly, efficient, and stable perovskite solar cells.
研究领域:
材料科学
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可再生能源
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太阳能电池技术
·
环境科学
✓ 已验证
DOI
高影响因子
Materials Today Communications
·
2022
·
IF 3.662
Weidong Li,Qiuyi Chen,Dongyun Zhang,Chen Fang,Song Nian,Wenxu Wang,Cong Xu,Chengkang Chang
Aiming for promoting the capacity and cycling stability of O3-type NaNi 1/3 Fe 1/3 Mn 1/3 O 2 (NFM), the cathode material of sodium ion batteries (SIBs) with the most potential for industrialization, Na(Ni 1/3 Fe 1/3 Mn 1/3 ) 0.99 Mo 0.01 O 1.99 F 0.01 (NFM-MoF), Na(Ni 1/3 Fe 1/3 Mn 1/3 ) 0.99 Mo 0.01 O 2 (NFM-Mo) and NaNi 1/3 Fe 1/3 Mn 1/3 O 1.99 F 0.01 (NFM-F) were successfully synthesized by solid phase method. The electrochemical performance of the doped samples was compared with that of the pristine NFM. The mechanism of the single- or dual-doping was explored by XRD Rietveld refinement and XPS. The NFM-MoF exhibits the highest initial specific discharge capacity of 137mAhg −1 at 1 C with a retention of 91.97% after 100 cycles and the smallest polarization (0.32 V), which could be contributed to the highest Ni 2+ content and highest D Na + (7.335 ×10 −13 cm 2 ·s −1 ) caused by the synergistic effect of Mo and F dual-doping. The highest Fe 3+ content in the NFM-Mo leads to the higher initial discharge capacity of 1 36 mAhg −1 at 1 C with a relative lower retention of 83.38%, which is due to the structure instability resulting from Fe migration and the lowest Mn content, than that of the NFM-F (85.31%). It illustrates that the Mn 4+ plays a crucial role in stabilizing the structure during Na + migrating. The superiority of the discharge capacity of the NFM-Mo become narrow with rates rise, due to its lower D Na + (4.229 ×10 −13 cm 2 ·s −1 ) than that of the NFM-F D Na + (5.681 ×10 −13 cm 2 ·s −1 ). It verifies that it is a diffusion control process at high rates. Mo and F dual-doping in NFM was proved to amplify the benefit of Ni 2+ increasing, meanwhile restrain undesirable Fe increasing due to the synergistic effect.
研究领域:
材料科学
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电化学
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储能技术
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无机化学
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固体物理
✓ 已验证
DOI
高影响因子
FUEL PROCESSING TECHNOLOGY
·
2021
·
IF 7.033
Hong Li,Jiajun Guo,Yuhao Zhang,Liang Zhao,Jinsen Gao,Chunming Xu,Haitao Pang,Pengfei Hao
The separation of aromatics from fluid catalytic cracking (FCC) diesel is of great significance for environmental protection. The extraction ability of 1-methyl-2-pyrrolidinone (NMP), sulfolane (SUL), and 4-formylmorpholine (NFM) were studied by the liquid-liquid equilibrium (LLE) experimental, and the corresponding LLE data of NMP/SUL/NFM + 1-methylnaphthalene + dodecane systems were obtained. The calculated distribution coefficients and separation factors showed that the solubility of 1-methylnaphthalene was the highest in NMP and the selectivity of SUL to 1-methylnaphthalene was the strongest. The effects of solvent structures were investigated by a combination of experiments and quantum chemical calculations . The 1-methylnaphthalene is more soluble in solvents with planar molecular structure because the steric hindrance between the two molecules is smaller, and the group with more electronegative has higher selectivity for 1-methylnaphthalene. Moreover, the reduced density gradient (RDG) and atoms in molecules (AIM) analyzed found that the main extraction mechanism of the three solvents was van der Waals (VDW) and weak hydrogen bond , in which VDW was dominant. Finally, the binary interaction parameters of NRTL and UNIQUAC models were obtained, which make up for the blank in Aspen simulation for the separation of FCC diesel by organic solvents.
研究领域:
环境科学
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化学工程
✓ 已验证
DOI
高影响因子
CHEMICAL PAPERS
·
2016
·Vol. 70
·期 5
·585-593
·
IF 1.326
Lin Zhu,Fang-Fang Li,Ji-Qin Zhu,Zhi-Gang Lei
Olefins and paraffins are important basic chemical raw materials with so similar molecular structure and volatility that their separation is a difficult and energy-consuming process. Liquid–liquid equilibrium (LLE) data were determined for ternary systems of: 1-hexene + hexane + solvent at 25°C, 30°C, and 35°C, and N-formylmorpholine (NFM), N-methyl-2-pyrrolidone (NMP), 7-butyrolactone (GBL), and 1-methylimidazole (1-MEI) as the solvents studied. Liquid–liquid equilibrium data for each system were correlated to the NRTL (Non-Random Two Liquid) equation and the interaction parameters presented. The calculated results agree well with the experimental data.
研究领域:
化学工程
·
物理化学
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）