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NH2-CAU-1
JOURNAL OF MATERIALS SCIENCE · 2024 ·Vol. 59 ·期 7 ·3177-3190 · IF 3.5

NH2-CAU-1 modified polyphenylene sulfone (PPSU) membrane for separation of oil-in-water emulsions

Lu Xiaohui,Yu Shouwu,Gao Tian,Chen Yifu,Zhao Xiang,Xiao Shujuan

The wettability of the membrane surface is very important for the separation of oil-in-water emulsion. In this paper, the hydrophilic NH 2 -CAU-1 was added to the membrane surface by interfacial polymerization, which greatly improved the separation efficiency of oil-in-water emulsion. The effect of the amount of NH 2 -CAU-1 on the separation efficiency of TFN membrane was studied, and it was determined that TFN-1 membrane had ultra-high separation efficiency of oil-in-water emulsion (> 97.60%). TFN-1 membrane has a high underwater oil contact angle (higher than 139.53°), resulting in excellent oil adhesion resistance on the membrane surface. The universality and cycling performance of TFN-1 membrane were tested, and UWOCA had good stability under strong acid, strong base and different NaCl concentrations, and the separation efficiency did not change significantly after 8 cycles. The results show that TFN-1 membrane has excellent performance in separating oil-in-water emulsions and has broad application prospects in separating oil-in-water emulsions stabilized by surfactants. Graphical abstract

研究领域: 膜科学 · 化学工程 · 材料科学 · 环境工程 · 分离技术
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