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Designing multivariate porphyrin-based metal-organic frameworks with Ni/Co dual-metal atom sites for cooperative NO2 capture and NO retention

Shanshan Shang,Chao Yang,Yuanmeng Tian,Zeyu Tao,Mallory Smith,Hongyan Zhang,Lin Zhang,Liangchun Li,Qinfen Gu,Hong-Cai Zhou,Yong Sik Ok,Jin Shang

Selective adsorption using porous materials is a promising approach to removing ambient nitrogen dioxide (NO 2 ). However, the highly reactive nature of NO 2 and the often-associated release of nitric oxide (NO) render a formidable challenge in developing effective and stable adsorbents. Here, we designed multivariate porphyrin-based metal–organic frameworks (MTV-PMOFs Al-PMOF(Ni x Co y )) featuring atomically dispersed Ni/Co dual-metal centers in the porphyrin ring as active adsorption sites, as robust adsorbents capable of synergistically boosting NO 2 adsorption capability and retaining the evolved NO. The introduction of the Ni/Co dual-metal sites in MTV-PMOFs greatly enhanced the NO x adsorption performance. Under dry conditions, Al-PMOF(Ni 1 Co 1 ) exhibited a NO 2 adsorption capacity of 3.66 mmol/g (100 ppm NO 2 in feed), among the highest under similar conditions, a high NO retention ability, and good regenrability (85%). Under wet conditions, its NO 2 removal capacity was further elevated by more than 50% (5.65 mmol/g). Moreover, the Ni/Co ratio in MTV-PMOFs dictates a structure–property relationship between the released amount of NO and adsorbed capacity of NO 2 . Such a corporative NO 2 and NO adsorption was for the first time established in MOFs. The material stability and potential economic value were also investigated to demonstrate the applicability of MTV-PMOFs as NO 2 adsorbents. This work provides new perspectives for the development of adsorption-based technology for mitigating ambient NO 2 pollution and managing other corrosive and toxic gases.