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Improved thermometry sensitivity of red-emitting SrGd2O4:Er3+,Yb3+ phosphors using novel NTCL-FIR technology based on 2H11/2 and 4F9/2

Shuangshuang Ding,Yongbiao Yan,Jianwei Zhou,Yangyang Hua,Hongxing Cai,Shuang Li

In this work, the upconversion luminescence (UCL) and temperature-sensing properties of SrGd 2 O 4 phosphors doped with Er 3+ , Yb 3+ were investigated. The UCL performance was studied by adjusting the doping concentrations of Er 3+ , Yb 3+ . It can be found that the intensity of red UCL is effectively improved by doping Yb 3+ ions. The band structures of SrGd 2 O 4 , SrGd 2 O 4 :5 mol%Er 3+ , and SrGd 2 O 4 :5 mol%Er 3+ ,15 mol%Yb 3+ were calculated using the density functional theory (DFT) to verify the experimental results. The thermal sensitivity of SrGd 2 O 4 :5 mol%Er 3+ ,15 mol%Yb 3+ phosphors was studied using the novel fluorescence intensity ratio of non-thermally coupled energy levels (NTCL-FIR) technique based on the 2 H 11/2 and 4 F 9/2 energy levels. The analytical results reveal that the maximum values of S r are 1.69%/K (300 K), 1.18%/K (300 K) and 1.47%/K (300 K) respectively under 915, 980 and 1550 nm excitations. The S r values of novel NTCL-FIR are compared with that of thermal coupling of energy level (TCL) and other studies in the same field. The results show that the thermometry sensitivity of red-emitting UCL materials can be enhanced by using the novel NTCL-FIR technique. In addition, the intense red UCL of SrGd 2 O 4 :Er 3+ ,Yb 3+ phosphors have the advantage of deeply penetrating biological tissues. Therefore, the combination of novel NTCL-FIR and red-emitting SrGd 2 O 4 :Er 3+ ,Yb 3+ phosphors could be conducive to temperature monitoring in vivo .