Synthesis of zirconium boride (ZrB2) rod crystals through salt-assisted boro/carbothermal reduction
High-aspect-ratio ZrB 2 rod crystals were synthesized via a molten-salt-mediated boro/carbothermal reduction using ZrOCl 2 · 8H 2 O/B 4 C/C as the raw material and NaCl as the flux material. This synthesis may improve the poor fracture toughness of monolithic ZrB 2 ceramics. X-ray diffraction and scanning electron microscopy confirmed that the heat-treatment temperature of 1550 °C and the addition of 50 wt% NaCl were the most effective in the preparation of ZrB 2 grains with a high aspect ratio. Thermogravimetric and differential scanning calorimetry was used to study the influence of NaCl addition, which increased the liquid-phase content. Finally, the growth of ZrB 2 grains along the c-axis into rod-like morphology at elevated temperatures was investigated by transmission electron microscopy . This work revealed that the addition of NaCl has a positive effect on the reducing of synthesis temperature and increasing of products particle size. The ZrB 2 rod crystals synthesized have diameters and aspect ratios of approximately 1 μm and 30, respectively.
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