Thermally enhanced luminescence of down-conversion NaScMo2O8:Eu3+ phosphor for white LEDs
The thermal quenching effect of phosphors imposed significant limitations on the applications of luminescent materials in high-temperature environments, which can lead to device performance degradation or even system failure. Currently, there was a lack of red phosphors that demonstrate high luminous efficiency, excellent stability, and high color purity, making them suitable for white light-emitting diodes (LEDs). Herein, a strategy to enhance luminescence at elevated temperatures was achieved by synthesizing Eu 3+ -doped monoclinic NaScMo 2 O 8 phosphors, whose structural, morphological, thermal, and optical properties were characterized by XRD, SEM, TG, and PL spectroscopy. A comprehensive investigation of the optical properties revealed a significant increase in luminescence intensity with high Eu 3+ concentrations. At a doping concentration of 3 mol%, the phosphor exhibited the strongest electric dipole transition ( 5 D 0 - 7 F 2 ) with a maximum emission peak at 614 nm. Between 30 °C and 270 °C, the red characteristic emissions of Eu 3+ gradually intensified with rising temperature, reaching up to 8 times the intensity at room temperature, while maintaining consistent fluorescence characteristics. These findings highlighted its potential application in white LEDs.
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