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Alcohol production from fatty acids via Ni3Fe/Rutile: Revealing the role of oxygen vacancy and metal-support electronic density characteristics

Feng Long,Shiyu Wu,Haitian Chen,Shuya Jia,Xincheng Cao,Peng Liu,Yanju Lu,Jianchun Jiang,Xiaolei Zhang,Junming Xu

Ni 3 Fe clusters anchored on rutile (R-TiO 2 ) were synthesized by hydrothermal (HT), coprecipitation (CP) and impregnation (IM) methods, and the catalytic performance of different NiFe/R-TiO 2 catalysts were investigated for hydrogenation of fatty acid into alcohol. Notably, HT-NiFe/R-TiO 2 catalyst, with the highest specific surface area and Ni 3 Fe nanoparticles dispersion, exhibited the best hydrogenation activity towards alcohol production, with complete conversion and yield reach of 92.5 % at 4 MPa H 2 , 210 ℃ and 6 h. The structure–reactivity relationship was investigated by a series of catalysts characterization, DFT calculation and corroborated through hydrogenation performance evaluations. Anchoring Ni 3 Fe clusters onto highly dispersed basic site surfaces with different Ov concentrations can change the electron distribution and strength of the metal-support interaction, causing more stable adsorption of the H and acids molecular toward fatty alcohol production. This work provides further insight into the structure–activity of NiFe/TiO 2 catalysts synthesized through different methods.