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Ni3S4/CuS
JOURNAL OF ALLOYS AND COMPOUNDS · 2022 · IF 6.371

Sandwich-like porous MXene/Ni3S4/CuS derived from MOFs as superior supercapacitor electrode

Hao Guo,Junye Zhang,Fan Yang,Mingyue Wang,Tingting Zhang,Yanrui Hao,Wu Yang

Metal-organic frameworks (MOFs) have ordered porous structure and intriguing properties for supercapacitors , however, poor conductivity and cycle stability limits their application. To solve these problems, hence, a simple strategy is proposed, by which MOFs are in-situ grown in the porous conductive p-MXene substrate. And then, along with the introduction of CuS, the grown Ni-MOF is derived to Ni 3 S 4 , which is more stable and more electrochemically active. Due to higher contact area, excellent synergistic effect and more exposed active sites, the prepared sandwiched p-MXene@Ni 3 S 4 /CuS nanostructure displays a big specific capacitance (1917 F·g −1 ) and superior cycling performance (91.2%@30000). What’s more, the assembled p-MXene@Ni 3 S 4 /CuS//AC asymmetric device delivers a high energy density of 87.62 Wh·Kg −1 at the power density of 775.02 W·Kg −1 , suggesting that this material provides a brilliant candidate for energy storage.

研究领域: 材料科学 · 能源存储
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