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NiCoP@Cu3P
Journal of Materials Chemistry A · 2017 ·Vol. 6 ·期 5 ·2100-2106 · IF 8.867

Forest-like NiCoP@Cu3P supported on copper foam as a bifunctional catalyst for efficient water splitting

Xingxing Ma,Yaqing Chang,Zhe Zhang,Jilin Tang

The design of cost-efficient earth-abundant catalysts with superior performance for electrochemical water splitting is highly desirable. Herein, we report a simple and effective approach to fabricate a high-performance NiCoP@Cu3P heterostructure on Cu-foam (NiCoP@Cu3P/CF) for the first time, which has synergistic active sites, large electrochemical surface area, small charge-transfer resistance, efficient mass transport and electron transfer for both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). The optimized NiCoP@Cu3P/CF exhibits a pretty low overpotential of 54 mV at 10 mA cm−2 and a small Tafel slope of 72 mV dec−1 serving as a HER electrocatalyst and also exhibits a low overpotential of 309 mV at 10 mA cm−2 and an extremely small Tafel slope of 42 mV dec−1 serving as an OER electrocatalyst in 1 M KOH.

研究领域: 材料科学 · 电化学
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