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Heterogeneous Non-noble Catalyst for Highly Selective Production of Linear α-Olefins from Fatty Acids: A Discovery of NiFe/C

Zihao Zhang,Wenwen Lin,Yafei Li,Francis Okejiri,Yubing Lu,Jixing Liu,Hao Chen,Xiuyang Lu,Jie Fu

Graphical Bimetallic boost : A NiFe/C bimetallic catalyst is reported, composed of NiFe alloy in the material bulk and a surface mixture of NiFe alloy and oxidized NiFe δ + species, exhibiting a heptadecene yield of 70.1 % with selectivity to 1-heptadecene as high as 92.8 % at just 190 °C. Catalytic deoxygenation of even-numbered fatty acids into odd-chain linear α-olefins (LAOs) has emerged as a complementary strategy to oligomerization of ethylene, which only affords even-chain LAOs. Although enzymes and homogeneous catalysts have shown promising potential for this application, industrial production of LAOs through these catalytic systems is still very difficult to accomplish to date. A recent breakthrough involves the use of an expensive noble-metal catalyst, Pd/C, through a phosphine ligands-assisted method for LAOs production from fatty acid conversion. This study presents a unique, cost-friendly, non-noble bimetallic NiFe/C catalyst for highly selective LAOs production from fatty acids through decarbonylative dehydration. In the presence of acetic anhydride and phosphine ligand, a remarkable improvement in the yield of 1-heptadecene from the conversion of stearic acid was found over the supported bimetallic catalyst (NiFe/C) as compared to corresponding monometallic counterparts (Ni/C and Fe/C). Through optimization of the reaction conditions, a 70.1 % heptadecene yield with selectivity to 1-heptadecene as high as 92.8 % could be achieved over the bimetallic catalyst at just 190 °C. This unique bimetallic NiFe/C catalyst is composed of NiFe alloy in the material bulk phase and a surface mixture of NiFe alloy and oxidized NiFe δ+ species, which offer a synergized contribution towards decarbonylative dehydration of stearic acid for 1-heptadecene production.