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NiWO4/WO3
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA · 2022 · IF 3.752

Pt-decorated NiWO4/WO3 heterostructure nanotubes for highly selective sensing of acetone

Yong-ping CUI,Ya-ru SHANG,Rui-xia SHI,Quan-de CHE,Jun-peng WANG

The heterostructured NiWO 4 /WO 3 nanotubes (Ni/W NTs) were synthesized by using a facile self-assembly method on the sacrificial polystyrene (PS) nanofibers templates. Then, the Pt-decorated NiWO 4 /WO 3 (Pt@Ni/W) composite NTs were obtained through using an ultrasonic mixing method. The experimental results display that the order of gas-sensing performance is Pt@Ni/W>Ni/W>WO 3 . The 2wt.%Pt@Ni/W-5 NTs indicate the supreme acetone-sensing response ( R air / R gas =58.4 at 100×10 −6 ) at 375 °C, which is 10.6 and 1.53 times that of the WO 3 and NiWO 4 /WO 3 NTs, respectively. Additionally, the 2wt.%Pt@Ni/W-5 NTs also exhibit the dramatically high selectivity toward acetone against ethanol, methanal, methanol, NH 3 and toluene. The Pt-decorated Ni/W NTs show the excellent responsivity and stability toward acetone, which is ascribed to the construction of heterostructured NiWO 4 /WO 3 and the spill-over effect of Pt nanoparticles.

CAS / MDL: 25249-54-1 9003-39-8
研究领域: 材料科学 · 纳米技术 · 传感器 · 化学工程
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