Synthesis, characterization, and properties of a polyhedral oligomeric octadiphenylsulfonylsilsesquioxane
A novel polyhedral oligomeric octadiphenylsulfonylsilsesquioxane (ODPSS) was synthesized from octaphenylsilsesquioxane and benzenesulfonyl chloride via a Friedel–Crafts reaction with a high yield. ODPSS was identified by Fourier transform infrared spectroscopy, 1 H-NMR, 13 C-NMR, 29 Si-NMR, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI–TOF MS), wide-angle X-ray diffraction, and elemental analysis to be a kind of polyhedral oligomeric silsesquioxane of a T 8 R 8 structure. ODPSS exhibited superior thermal stability according to thermogravimetric analysis. Its initial thermal decomposition temperature ( T onset ) was at 491°C in air and 515°C in nitrogen. Thermal and mechanical properties of epoxy resin (EP) composites with ODPSS added were studied by differential scanning calorimetry and tensile testing. The results show that the incorporation of ODPSS at a low loading content not only improved the glass-transition temperature of the EP composites but also enhanced their tensile strength. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40892.
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