Novel double cross-linked membrane based on poly (ionic liquid) and polybenzimidazole for high-temperature proton exchange membrane fuel cells
Novel double cross-linked composite membranes are fabricated based on diazoniabicyclo-type poly (ionic liquid) with trimethoxysilane groups ([TSPDO]BrCl) and norbornene-type polybenzimidazole (NbPBI). During membrane fabrication, in-situ free radical polymerizations and in-situ sol-gel reactions are completed to form the poly (ionic liquid)-NbPBI cross-linked networks and the Si-O-Si networks, respectively. An obvious advantage of this strategy is that the trimethoxysilane groups are fixed by the first cross-linked networks before hydrolysis reaction . Such method can avoid structural defects caused by SiO 2 particle aggregation in the membranes. Compared to the pristine NbPBI cross-linked membrane, the NbPBI-TSPDO cross-linked membranes exhibit enhanced thermal stability, mechanical properties, and proton conductivity . Considering the comprehensive performance, the NbPBI-TSPDO 30 membrane has the highest proton conductivity of 0.061 S cm −1 at 170 °C under anhydrous conditions. Moreover, NbPBI-TSPDO membranes display an improved PA retention rate of up to 81% and 64% at 160 °C for 400 h and 80 °C/40% RH for 96 h, respectively.
危险品化学品经营许可证（带存储）