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PFDTES
SURFACE & COATINGS TECHNOLOGY · 2017 · IF 2.589

High performance super-hydrophobic ZrO2-SiO2 porous ceramics coating with flower-like CeO2 micro/nano-structure

Xue-Ling Wei,Na Li,Wen Jun Yi,Li-Jun Li,Zi-Sheng Chao

The super-hydrophobic (SH) porous ceramics material with good stability was successfully prepared via the hydrothermal growth of CeO 2 micro/nano-structure and the subsequent dip-coating of low surface energy substance 1H,1H,2H,2H-perfluorodecyltriethoxysilane (PFDTES) over the surfaces of ZrO 2 -SiO 2 porous ceramics substrate. The surface morphology , chemical composition and wettability of material were investigated by means of SEM, EDS, XRD , FT-IR, and contact angle measurement. It was found that a layer of CeO 2 nano-flowers had been attached over the surfaces of ZrO 2 -SiO 2 porous ceramics substrate, using the optimized concentration of CeNO3 precursor, and after the grafting of PFDTES, the super hydrophobicity of the obtained material was achieved, with the water contact angle being as high as 162° and sliding angle being approximately 0°. Particularly, the super hydrophobicity was found to occur also in the pores of the obtained material. The obtained material was found to possess the significantly large thermal and chemical stabilities.

研究领域: 材料科学 · 表面工程
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SEPARATION AND PURIFICATION TECHNOLOGY · 2025 · IF 9

Fabrication of PFDTES/BiOI/Bi5O7I/WPU photocatalytic self-cleaning coatings for NO green degradation

Huiyun Xia,Zeliang Wu,Wenshuo Zhang,Lifang Song,Xu Li,Liying Cui,Yanhui Niu

In this study, a BiOI/Bi 5 O 7 I photocatalyst is synthesized using a co-precipitation method. The degradation efficiency of NO can reach 70 % under visible light. Subsequently, water-based polyurethane is used as the film-forming matrix, and fluorinated silane is used as low surface energy components, a BiOI/Bi 5 O 7 I water-based polyurethane photocatalytic superhydrophobic coating (FBIU) is prepared by a layer-by-layer spraying technique. The high catalytic activity of BiOI/Bi 5 O 7 I comes from the heterojunction effect of the two semiconductors and the improved interface, which enables the degradation rate of NO to reach 76.9 %, accompanied by extremely low NO 2 conversion rate (<1 %). The wettability, chemical stability and mechanical stability of the FBIU coating are studied to investigate its impact on the long-term oxidative degradation performance of NO. And the self-cleaning characteristics and specific micro-nano structure of FBIU improve the wear resistance of the coating, manifested as a contact angle of 157.8° to water after 320 times of sandpaper polishing. Finally, based on the photocatalytic mechanism of BiOI/Bi 5 O 7 I semiconductor materials, a green long-term purification and degradation mechanism of NO by coatings is proposed. This can provide some insights into the design of air purification coatings for building exterior walls.

研究领域: 材料科学 · 环境科学 · 化学工程
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Materials · 2023 ·Vol. 16 ·期 10 ·3774 · IF 3.4

Fabrication and Experimental Study of Micro/Sub-Micro Porous Copper Coating for Anti-Icing Application

Jingxiang Chen,Cheng Fu,Junye Li,Weiyu Tang,Xinglong Gao,Jingzhi Zhang

Micro and sub-micro-spherical copper powder slurries were elaborately prepared to fabricate different types of porous coating surfaces. These surfaces were further treated with low surface energy modification to obtain the superhydrophobic and slippery capacity. The surface wettability and chemical component were measured. The results showed that both the micro and sub-micro porous coating layer greatly increased the water-repellence capability of the substrate compared with the bare copper plate. Notably, the PFDTES-fluorinated coating surfaces yielded superhydrophobic ability against water under 0 °C with a contact angle of ~150° and a contact angle of hysteresis of ~7°. The contact angle results showed that the water repellency of the coating surface deteriorated with decreasing temperature from 10 °C to −20 °C, and the reason was probably recognized as the vapor condensation in the sub-cooled porous layer. The anti-icing test showed that the ice adhesion strengths of the micro and sub-micro-coated surfaces were 38.5 kPa and 30.2 kPa, producing a 62.8% and 72.7% decrease compared to the bare plate. The PFDTES-fluorinated and slippery liquid-infused porous coating surfaces both produced ultra-low ice adhesion strengths of 11.5–15.7 kPa compared with the other non-treated surfaces, which showed prominent properties for anti-icing and deicing requirement of the metallic surface.Keywords:superhydrophobic surface;anti-icing;porous coating;wettability

研究领域: 材料科学 · 表面工程 · 防冰技术
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Journal of Materials Research and Technology-JMR&T · 2024 · IF 6.2

Waterborne robust superhydrophobic PFDTES@TiO2-PU coating with stable corrosion resistance, long-term environmental adaptability, and delayed icing functions on Al-Li alloy

Xuewu Li,Chenghu Ma,Tian Shi,Hejie Yang,Chuanwei Zhang,Wei Qi,Chen Li,Rongrong Liu,Weiping He,Yuanhai Liu

Aluminum-Lithium (Al-Li) alloys widely used in aerospace manufacture are highly susceptible to corrosion, which limits their industrial applications. Herein, 1H,1H,2H,2H-perfluorodecyltriethoxysilane (PFDTES) is used as a modifier for low-surface-energy treatment of TiO 2 nanoparticles. The water-based polyurethane (PU) is made as a binder to achieve a tight bonding between modified ceramic particles and Al-Li alloy, thus resulting in the extremely-feasible air-spraying preparation of a superhydrophobic coating with strong abrasion resistance. The water contact angle (CA) of as-prepared coating achieves 160 ± 0.83°, and the rolling angle (SA) is as low as 5.95 ± 0.59°. The surface structure, organization and composition are further characterized using SEM, EDS, XPS and laser confocal microscopy. Meanwhile, the electrochemical impedance and potentiodynamic polarization tests are performed for corrosion characterization. The results show that the corrosion potential of such coating increases by 170 mV compared with substrate, the corrosion current density decreases by two orders of magnitude, and the impedance modulus increases by two orders. The corrosion inhibition rate of the as-prepared coating is 98.8%, indicating that the corrosion resistance has been significantly enhanced. In addition, the mechanical robustness and stability of the coating is evaluated and confirmed using a sandpaper rubbing test. It also possesses great self-cleaning, anti-pollution and thermostable behaviors, thereby allowing them to work in extreme manufactures. Moreover, the as-prepared coating exhibits excellent adaptability to various materials and anti-icing property. This work sheds positive insights in enlarging industrial applications of multifunctional ceramic coatings in aerospace fields.

CAS / MDL: 81-88-9
研究领域: 材料科学 · 航空航天工程 · 表面工程
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MATERIALS RESEARCH BULLETIN · 2024 · IF 5.3

Superhydrophobic photothermal evaporator based on MoS2 nanoflowers for efficient solar desalination

Fang Xing,Satheesh kumar Balu,Panpan Zhang,Ruimin Xing

Solar desalination is a promising solution to address global water scarcity. In this study, a novel superhydrophobic photothermal evaporator based on MoS 2 nanoflowers, known for their excellent photothermal conversion properties. The evaporator was developed is coated with 1H, 1H, 2H, 2H-Perfluorodecyltriethoxysilane (PFDTES) to create superhydrophobic structures, which are then loaded onto a macroporous non-woven fabric (NWF) to facilitate efficient steam release. The hydrophobic PFDTES coating effectively prevents salt crystallization, ensuring long-term desalination. The developed device demonstrates an exceptional solar steam generation performance of 1.52 kg·m −2 ·h −1 with an evaporation efficiency of up to 87.1%. This evaporator offers a promising solution to water scarcity challenges due to its high evaporation efficiency, impressive durability, and low-cost.

研究领域: 材料科学 · 环境工程 · 太阳能 · 水处理
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CARBOHYDRATE POLYMERS · 2025 · IF 12.5

Preparation and characterization of anti-fingerprint and antireflective coatings prepared for touchscreen displays based on chitin nanofibers

Li Zhang,Lili Ren,Wei Song,Shuai Wang,Qiancheng He,Nan Wu,Jiang Zhou

The rapid development of touchscreen interfaces and portable electronics has increased the demand for anti-fingerprint and antireflective coatings, which enhance screen visibility and improve the user's visual experience. However, existing oleophilic or oil-repellent coatings often fail to deliver both high transparency and durable anti-fingerprint performance under real-use conditions. In this study, an antireflective coating was fabricated based on chitin nanofibers (ChNFs) to provide both amphiphobic and anti-fingerprint protection for touchscreen displays. The ChNF-based coatings with abundant large-sized nanopores were fabricated via freeze casting and subsequent modification with PFDTES deposition. The PFDTES-modified chitin nanofiber (P-ChNF) coatings combined the anti-fingerprint performance of both water and oleic acid contact angles of 153° and 118°, and increased glass transmittance at 550 nm by ~5 %. The P-ChNF coatings possessed good environmental durability and mechanical robustness, maintaining their anti-fingerprint and antireflective properties under harsh conditions. Notably, the smartphone screen coated with P-ChNF exhibited a substantial reduction in fingerprint residue, confirming improved anti-fingerprint performance. This work not only demonstrates that ChNFs are a promising candidate for meeting the growing demand for protective coatings in touchscreen displays, but also offers a feasible and efficient strategy to do so, thereby promoting the green and sustainable development of the anti-fingerprint coating industry.

研究领域: 材料科学 · 纳米技术 · 涂层与表面工程 · 光学材料 · 可持续材料
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