Jian Chen,Zhiqiang Cheng,Yafeng Yuan,Jingjing Zhang,Jinshan Cao
In this study, design and fabrication of novel shape-controllable and aligned nanofibrous membranes with self-cleaning and robust mechanical properties is presented. Smooth and uniform nanofibers can be fabricated by blending polyamide 66 (PA66) and poly (vinyl butyral) (PVB) with a mass ratio of 6/4 during electrospinning. Subsequently, the prepared nanofibrous membranes were placed in a vacuum drying oven at a given temperature (90 °C) for heat treatment, and the morphology of the composite nanofibers was controlled by an external tensile force. It was found that the treatment temperature and external tensile force greatly affected the pore structures and orientation of the nanofiber membranes. In addition, the hydrophobicity, pore structure and mechanical properties of well-aligned nanofibrous membranes are better than those of non heat-treatment nanofibers. Moreover, the PA66/PVB nanofibrous membranes are used as air filters, and show an excellent removal efficiency of up to 99.99% for PM2.5.
Xue Yang,Yi Pu,Shuxia Li,Xiaofang Liu,Zheshan Wang,Ding Yuan,Xin Ning
To address the challenge of high-temperature air filtration, a novel electreted polysulfonamide/polyacrylonitrile-boehmite (PSA/PAN-B) composite nanofiber based filter was developed via electrospinning for effective high-temperature dust removal. In this study, the spinnability of PSA was greatly improved by adding a small amount of PAN as an auxiliary polymer, and the introduction of a boehmite electret further significantly reinforced the properties of PSA fibers. As a result, the PSA/PAN-B membrane exhibited a high filtration efficiency (up to 99.52 ± 0.32%), low pressure drop (45.16 ± 1.39 Pa), excellent flexibility, good mechanical properties, high thermal stability (up to approximately 300 °C), and superior chemical resistance. Through data analysis and 3D simulation, the important benefits of the boehmite electret in the optimization of the PSA fibrous membrane performance were determined: it increases the charge storage capacity, constructs a rough surface morphology, improves the specific surface area, and enhances the mechanical properties. More importantly, the PSA/PAN-B film possessed a robust PM2.5 purification capacity, and the particulate matter removal efficiency was kept unchanged after high-temperature, acid, or alkali treatment—a performance derived from the intrinsic molecular structure of PSA. The PSA/PAN-B composite fibrous membrane, with excellent comprehensive properties, is a promising candidate for air filters, especially in harsh environments, further broadening the applications of PSA and providing new insight into the design of high-performance filters with high-temperature and corrosion resistance.
Shanshan Ma,Meiyun Zhang,Jingyi Nie,Jiaojun Tan,Bin Yang,Shunxi Song
A biodegradable cellulose-based air filter (Ag-MOFs@CNF@ZIF-8) with multi-layer structure was fabricated by in situ generation of double-component metal-organic frameworks (MOFs) and reinforcement of cellulose nanofiber (CNF). It exhibits good filtration performance, gas adsorption, antibacterial activity and mechanical property. The presence of MOFs could enhance the interaction between the filter and particulate matter (PM) and significantly improve the specific surface area of the composite filter. Thus, the filtration efficiency of the composite filter could reach 94.3% for PM 2.5 and the nitrogen adsorption capacity increased to 109 cm 3 g −1 . Furthermore, the Ag-MOFs@CNF@ZIF-8 filter exhibited excellent antibacterial activity against Escherichia coli with an inhibition zone diameter of 18.1 mm. The compressive strength of the composite filter could be up to 501 kPa, approximately 3.8 times higher than that of pure cellulose filter. Herein, this composite filter has a great application potential in PM 2.5 removal, toxic gas adsorption and healthcare fields.
危险品化学品经营许可证（带存储）