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POLYMER ENGINEERING AND SCIENCE · 2023 ·Vol. 63 ·期 2 ·489-498 · IF 3.2

Effect of polymer molecular structure on the quality of thin-walled hollow microspheres for inertial confinement fusion

Wenting Xu,Qianqian Gu,Fanghua Zhu,Qiang Chen,Yiyang Liu,Jie Li,Meifang Liu,Yong Yi

Polymer microspheres can be used as fuel containers for laser inertial confinement fusion (ICF) due to their low atomic number, low density, and high thermal stability. The thin-walled polymer microspheres are prone to cracking due to an increase in the diameter to thickness ratio (diameter/wall thickness). The effect of polystyrene (PS) and Poly (α-methyl styrene) (PAMS) materials commonly used in ICF experiments on the quality of thin-walled microspheres is investigated. PS hollow microspheres show better sphericity, smoother surface, and lower cracking rate than PAMS microspheres. Moreover, the heat treatment of solidified PS microspheres can improve the strength so that the cracking rate of the microspheres decreases. The relative mechanism of how the molecular structure affect the quality is also discussed. This study provides some guidance for the preparation of thin-walled polymer microspheres with high quality for ICF experiments.

CAS / MDL: 462-06-6
研究领域: 材料科学 · 核物理学
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ENVIRONMENTAL TECHNOLOGY · 2025 · IF 2

Portable water collection bag based on solar-driven interfacial evaporation

Ye Jia,Lingxue Kong,Tengdi Zhang,Yuping Wang,Anmin Liu,Liguo Gao,Tingli Ma

Convenient and portable, sustained provision of safe drinking water is crucial for wilderness survival. In this study, a portable water collection bag utilising solar-driven interface evaporation technology has been developed. The water collection bag includes a plastic film, CB-PS microsphere evaporator, and a small vial. By placing on the water surface, the CB-PS microspheres float and absorb sunlight to quickly evaporate the surrounding water. The plastic film and vial make it easy and fast to collect clean and safe drinking water. The device boasts an impressive evaporation rate of 1.64 kg·m⁻²·h⁻¹ under 1 sun illumination. Moreover, the portable water collection bag can withstand harsh acidic and alkaline conditions, efficiently removing organic contaminants from wilderness water sources to meet drinking water standards. Importantly, it is designed for repeated use without any water evaporation rate decreasing. The portable water collection bag also exhibits strong resistance to salt, making it suitable for applications in desalinating seawater into freshwater.

研究领域: 材料科学 · 环境科学 · 水资源管理
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JOURNAL OF CRYSTAL GROWTH · 2018 · IF 1.742

Fabrication of large scale PS monolayer colloidal crystal film by using a novel secondary self-assembly method for nanoimprint technique

Xuehua Zhang,Liang Yu,Wei Zhang,Fangren Hu,Yongjin Wang

PS microspheres emulsions with different PS diameters of 207 and 378 nm were prepared by using an emulsifier-free polymerization method. A novel secondary self-assembly method which combined the spin coating and the lifting-up method was used to prepare the close-packed PS MCC films. During the process, the PS MCC film was firstly assembled on a glass substrate by a spin coating technique. Secondly, the obtained PS MCC film was transferred on the air-water interface by immersing the PS glass substrate in water using a dip-coater. Thirdly, the floating close-packed PS MCC films on the air-water interface was transferred to a new glass substrate by using a lifting-up method. During the spin-coating and the self-assembly process, some SDS solution was added in the PS films to improve the uniformity of the PS layer. Effects of the spin-coating speeds, the SDS solution concentration and the lifting-up rates on the morphology of PS MCC films have been discussed. Scanning electron microscopy was used to observe the morphological properties of the PS colloidal crystal films. Results indicate that a relatively close-packed and large scale PS MCC films can be obtained when the spinning speed is 2000 rpm for 60 s, the SDS solution concentration is 2 wt% and the lifting-up rate is 2 mm/min. Furthermore, the polydimethylsiloxane soft mold was replicated from the-fabricated PS MCC films and was then imprinted onto the photosensitive hybrid film under UV-irradiation and thus the micro-lens arrays built in the photosensitive hybrid sol–gel film were obtained.

研究领域: 材料科学 · 纳米技术
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RSC Advances · 2023 ·Vol. 13 ·期 19 ·12966-12972 · IF 3.9

Ultrasensitive electrochemical biosensor for detection of circulating tumor cells based on a highly efficient enzymatic cascade reaction

Min Dong,Zhihong Gao,Yating Zhang,Jiahui Cai,Jian Li,Panpan Xu,Hong Jiang,Jianmin Gu,Jidong Wang

There has been great interest in the enzymatic cascade amplification strategy for the electrochemical detection of circulating tumor cells (CTCs). In this work, we designed a highly efficient enzymatic cascade reaction based on a multiwalled carbon nanotubes–chitosan (MWCNTs–CS) composite for detection of CTCs. A high electrochemical effective surface area was obtained for a MWCNTs–CS-modified glassy carbon electrode (GCE) for loading glucose oxidase (GOD), as well as a high loading rate and high electrical activity of the enzyme. As a ‘power source’, the MWCNTs–CS composites provided a strong driving power for horseradish peroxidase (HRP) on the surface of polystyrene (PS) microspheres, which acted as probes for capturing CTCs and allowed the reaction to proceed with further facilitation of electron transfer. Aptamer, CTCs, and PS microspheres with HRP and anti-epithelial cell adhesion molecule (anti-EpCAM) antibody were assembled on the MWCNTs–CS/GCE to allow for the modulation of enzyme distance at the micrometer level, and thus ultra-long-range signal transmission was made possible. An ultrasensitive response to CTCs was obtained via this proposed sensing strategy, with a linear range from 10 cell mL−1 to 6 × 106 cell mL−1 and a detection limit of 3 cell mL−1. Moreover, this electrochemical sensor possessed the capability to detect CTCs in serum samples with satisfactory accuracy, which indicated great potential for early diagnosis and clinical analysis of cancer.

研究领域: 生物传感器 · 癌症诊断 · 电化学 · 纳米技术 · 生物医学工程
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