Synthesis of poly(N1,N1,N6,N6-tetraallylhexane-1,6-diammonium dichloride) microparticles for removing Mo(VI) in aqueous solution
A novel poly(N 1 ,N 1 ,N 6 ,N 6 -tetraallylhexane-1,6-diammonium dichloride) (PTAHDADC) microparticle was prepared via inverse emulsion polymerization . The adsorption characteristics and mechanism for Mo(VI) in an aqueous solution were investigated systemically. Results showed that PTAHDADC had a high positively charge density with a positive charge at every six CH 2 (or CH ) units and presented a coral-like morphology, with macropores distributed in 30–130 μm, and a porosity of up to 46.52%. The Mo(VI) removal efficiency was >99% at pH = 3.0–4.0. The adsorption data could be effectively described using the Langmuir and pseudo-second-order kinetic models . The maximum adsorption capacity was up to 394.11 mg·g −1 at 293 K. The adsorption process was rapid, and reached equilibrium within 120 min with an adsorption activation energy E a of 41.15 kJ·mol −1 . The adsorption process of Mo(VI) by PTAHDADC was accompanied by the partial ion exchange of counterion Cl − , the partial deprotonation of functional groups ( CH 2 ) 3 N + H on PTAHDADC, and the new interaction and bond formation between Mo(VI) and PTAHDADC. Mo(VI) removal by PTAHDADC was a process of spontaneously endothermic entropy increment, which involves physisorption , electrostatic attraction, ion exchange, and chemisorption . PTAHDADC offers a simple synthesis and excellent adsorption performance and recyclability. Therefore, PTAHDADC is a highly potential adsorbent for removing Mo(VI) ions from wastewater and has a broad application prospect.
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