PVDF/PS/HDPE/MWCNTs/Fe3O4 nanocomposites: Effective and lightweight electromagnetic interference shielding material through the synergetic effect of MWCNTs and Fe3O4 nanoparticles
In this work, Polyvinylidene Fluoride (PVDF)/polystyrene (PS)/high density polyethylene (HDPE) ternary blends displayed a core-shell structure where HDPE was the core, PS was the shell, and this core-shell system dispersed in PVDF matrix. Here, multiwall carbon nanotubes (MWCNTs) and ferroferric oxide (Fe 3 O 4 ) was incorporated. F-F composites with MWCNTs was in PS shell and Fe 3 O 4 was in PVDF matrix and E-F composites with MWCNTs was in PS shell and Fe 3 O 4 was in HDPE core were fabricated by melt blending. It was indicated that the core-shell morphology between PS and HDPE was well retained with the incorporation of Fe 3 O 4 and MWCNTs. Both the electrical conductivity of F-F and E-F composites were similar without no obvious change with the incorporation of Fe 3 O 4 . Composites with greater than 20 dB shielding effectiveness were easy to obtain. The highest SE we observed was for the F-F composite with 1 vol% Fe 3 O 4 and 1 vol% MWCNTs was 25 dB at 9.5 GHz, and the SE was over 20 dB in the whole measured frequency(X-band). The E-F composites with SE greater than 20 dB in X-band was at 2 vol% Fe 3 O 4 and 1 vol% MWNCTs. Such effective and lightweight nanocomposites were obtained, resulting from the synergetic effect of MWCNTs and Fe 3 O 4 nanoparticles .
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