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PVDF-PVC复合膜
Materials Research Express · 2020 ·Vol. 8 ·期 1 ·015303 · IF 1.929

Preparation, characterization and optimization of superhydrophobic PVDF-PVC composite membrane based on concentration change of casting solution

Dashuai Zhang,Xiaoxue Lin,Yan Zhang,Xiaopeng Zhang,Chen Li,Yang Lin,Tianyi Sun,Linhua Zhu,Qiang Lin,Zaifeng Shi

The PVDF/PVC superhydrophobic composite membrane was prepared by non-solvent induced phase separation method. When the concentration of PVDF/PVC(= 85/15) is 4%, DMF can be used as a solvent to prepare PVDF/PVC superhydrophobic composite membrane by using the simple and applicable NIPS method. Through static contact angle and rolling angle, it was found that the maximum contact angle of PVDF/PVC composite membrane with low concentration can reach 152°, rolling angle is 3 degrees, and the surface potential energy is also relatively low about 8°. It was found by DSC that the crystallinity of PVDF/PVC composite membrane with low concentration was higher, SEM shows that the surface of 4% PVDF/PVC composite membrane has nano scale protrusion, and AMF finds that the surface of 4% PVDF/PVC composite membrane was high Surface roughness. When the surface roughness was high, the surface hydrophobicity is improved, the wetting problem was alleviated, the self-cleaning ability of the membrane is improved, and the membrane pollution is reduced. It was found that the 4% PVDF/PVC composite membrane prepared by low concentration method has a long-lasting self-cleaning performance and can be used as an organic coating in the field of self-cleaning.

CAS / MDL: 68-12-2 9002-86-2
研究领域: 材料科学 · 膜技术 · 表面工程
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