JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
·
2021
·
IF 2.993
Jinxiang Guo,Zhaofei Tong,Qihua Liang,Fangyu Gan,Lepeng Wei,Qingrong Yao,Jianqiu Deng,Zhao Lu,Huaiying Zhou
Bi 1-x Pr x FeO 3 material with perovskite structure was prepared using organic tartaric acid-assisted sol–gel self-propagating combustion method to obtain high-efficiency microwave absorption materials. The influence of the introduction of Pr on dielectric properties and permeability was further studied. After 15% Pr introduced, the lowest reflection absorption loss reaches –32.34 dB, but the absorption bandwidth is only 2.25 GHz. When Pr is 5%, the lowest reflection absorption loss value of −27.31 dB is obtained, and the effective bandwidth which below −10 dB is 3.41 GHz. The structural changes in the process of Pr replacing Bi were analyzed to explore the properties of BPFO perovskite. The influence of strong interaction force, residual magnetization, and natural resonance of ceramic nanoparticles on microwave absorption performance was explored. This work supplies a reliable candidate material for making up electromagnetic attenuation ceramic materials with excellent properties.
研究领域:
材料科学
·
电磁学
✓ 已验证
DOI
高影响因子
Materials
·
2022
·Vol. 15
·期 19
·6953
·
IF 3.748
Yaohui Xu,Pingkeng Wu,Mingjin Wu,Yuehe Gu,Hongguang Yu,Zhao Ding
Pr-doped CeO2with different doping levels was prepared from Ce(NO3)3∙6H2O and Pr(NO3)3∙6H2O by solvothermal method without any additional reagents, in which the mixed solution of ethylene glycol and distilled water was employed as a solvent. The influences of Pr-doping on phase composition, crystal structure and morphology were investigated, as well as Pr valence and oxygen vacancy defects. The Pr cations entered into the CeO2crystal lattice with normal trivalence and formed a Pr-CeO2solid solution based on the fluorite structure. The larger trivalent Pr was substituted for tetravalent Ce in the CeO2crystal and compensated by oxygen vacancy defects, which caused the local lattice expansion of the crystal lattice. Moreover, the Pr-doped CeO2solid solutions exhibited visible color variation from bright cream via brick red to dark brown with the increasing of Pr contents. The degradation of AO7 dye was also investigated using a domestic medical ultraviolet lamp; the removal efficiency of AO7 by 1% and 2% Pr-doped CeO2approached 100%, much higher than 66.2% for undoped CeO2.Keywords:CeO2;Pr-doping;photocatalysis;pollutant degradation;mesoporous structure
研究领域:
材料科学
·
环境科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
·
2021
·
IF 5.316
Yongqing Wang,Fanbing Lai,Qikun Wang,Qinghua Long,Chao Wang,Wenjie Zhang,Qibing Chang
In this paper, high color performance Pr cation doped zircon (Pr-ZrSiO 4 ) yellow pigment has been prepared by inorganic sol-gel method. Meanwhile, the detailed process parameters for preparation of Pr-ZrSiO 4 pigment were systematically investigated. The research results indicate that the optimal process parameters are Pr-doping amount of 6 mol.%, calcination temperature of 900 °C, holding time of 2 h and Si/Zr ratio of 1.05. The synthesized Pr-ZrSiO 4 pigment shows an intense yellow hue, which chromatic parameters are L* = 81.84, a* = 4.36, b* = 70.55 and C* = 70.68. Moreover, the pigment shows outstanding tinting performance for ceramic glaze , suggesting its attractive application in ceramic decoration. XPS analysis demonstrated that the Pr cations in the Pr-ZrSiO 4 pigment consists of two valence states, namely trivalent and tetravalent. Finally, heterogeneously distributed behavior of Pr cations in the pigment was discovered.
研究领域:
材料科学
·
无机化学
✓ 已验证
DOI
高影响因子
Journal of Energy Storage
·
2024
·
IF 8.9
Yize Li,Weiqiang Zhou,Xuemin Duan,Danqin Li,Jingkun Xu,Zian Huang,Xiaojing Hao
Exploring high-performance metal oxide electrode materials is an essential way to boost the supercapacitor performance, and metal atom doping can significantly increase oxygen vacancies to improve the conductivity of electrode materials. A hydrothermal method is proposed for the preparation of sea urchin-like Pr-doped W 18 O 49 . A series of characterizations detected that Pr-doped W 18 O 49 produced significant lattice distortion and more amorphous regions, and the better electrochemical performance came from the increased concentration of oxygen vacancies, enlarged lattice spacing, higher specific surface area, and faster ion transport after Pr doping. Electrochemical measurements indicate that the specific capacitance of Pr-doped W 18 O 49 is improved from 381 F g −1 to 453 F g −1 at 3 A g −1 and exhibits a remarkable capacity retention of 95.6 % over 4000 cycles. An asymmetric supercapacitor assembled with this electrode and PPy achieved a high energy density of 21.9 Wh kg −1 at a power density of 701.5 W kg −1 , indicating the significance of Pr-doped W 18 O 49 for energy conversion and storage applications.
研究领域:
材料科学
·
能源存储
·
电化学
✓ 已验证
DOI
高影响因子
Materials Today Communications
·
2024
·
IF 3.7
Bing-Jie Wang,Xing Zhang,Jian Tang,Yi-Lei Li,Mu Lan,Wen-Ning Ren,Xin Chang,Sheng-Jiang Huang,Yan Jiao,Ruo-Ding Mao,Xiao-Hui Wu,Le-Zhong Li
With the miniaturization, chip, and integration of electronic products, the working frequency of electronic components is also getting higher and higher, which puts forward requirements for us to seek high-frequency materials with higher performance. To enhance NiZnCo ferrite properties, this study introduced the rare earth element Pr for modification and thoroughly examined its impact. The material Ni 0.55 Zn 0.3 Co 0.15 Pr x Fe 2- x O 4 (NZCPF, 0 ≤ x ≤ 0.1) was synthesized by sol-gel self-propagating technique. The X-ray diffraction of NZCPF indicates that Pr 3+ doped NiZnCo ferrites still keep the cubic spinel structure. With the increasing substitution of Pr 3+ ions in NiZnCo ferrite, the average grain size of the sample decreases from 1.05 μm to 0.73 μm. After the addition of Pr 3+ ions, the dielectric loss takes its minimum value (0.41@100 Hz), and the DC resistivity ρ takes its maximum value (4×10 6 Ω·m@30℃). The value of μ' (@10 MHz) monotonically decreases from 11.9 to 5.9 as the doping amount of Pr 3+ ions, denoted by x , increases. The saturation magnetization intensity decreases from 68.05 to 58.45 emu/g, and maximum magnetic loss decreases about 30% (0.65@1 GHz). It is worth noting that the resonance frequency f r increases from 343 MHz to 638 MHz with x increases, which is a substantial improvement compared to previous studies. Generally, the introduction of Pr 3+ ions into NiZnCo ferrite results in outstanding electromagnetic characteristics, offering a valuable reference to the advancement of compact and high-frequency devices.
研究领域:
材料科学
·
电磁学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
·
2019
·Vol. 30
·期 6
·5771-5779
·
IF 2.195
Liu Heng,Zheng Shuaizhi,Chen Qiang,Zeng Binjian,Jiang Jie,Peng Qiangxiang,Liao Min,Zhou Yichun
HfO 2 thin films with different praseodymium doping contents (Pr:HfO 2 ) were fabricated by chemical solution deposition (CSD) method at ambient conditions. The chemical bonding and the composition of Pr doped HfO 2 thin film were characterized by X-ray photoelectron spectroscopy (XPS), while the structural properties were investigated by glancing incidence X-ray diffraction (GIXRD) and high resolution transmission electron microscopy (HRTEM). It is found that the ferroelectric orthorhombic phase was induced in the HfO 2 based thin films by Pr doping. The combined results of P–E (polarization–electrical field) and C–V (capacitance–voltage) measurements demonstrated that the 5 mol% Pr doped HfO 2 film exhibited a distinct ferroelectricity, with a maximum remanent polarization ( P r ) of 6.9 µC/cm 2 and a coercive field ( E c ) of 1.2 MV/cm. Notably, the polarization did not show obvious degradation over 1 × 10 8 switching cycles, suggesting good endurance performance of the Pr doped HfO 2 thin film. These results indicate that Pr dopant could effectively induce ferroelectricity in HfO 2 thin films, thereby becoming a new member of dopants for HfO 2 based ferroelectrics.
研究领域:
材料科学
·
电子工程
✓ 已验证
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
·
2016
·Vol. 27
·期 7
·6829-6834
·
IF 1.798
Su Chang,Li Yu,Li Shouchun,Liu Li,Guo Xuexin,Lian Hongwei,Guan Xiulong
Pure and Pr-doped α-Fe 2 O 3 nanotubes are successfully synthesized via electrospinning and following calcined method. The crystal, morphologies structures and composed of the as-prepared samples are investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS), respectively. The researches of the gas sensing properties of the samples show that Pr-doped α-Fe 2 O 3 nanotubes possess excellent sensitive to ethanol, and the response value of Pr-doped α-Fe 2 O 3 nanotubes to 10 ppm ethanol is 21.3 at the operating temperature 240 °C, which is much higher than that of pure α-Fe 2 O 3 nanotubes (1.5). That is to say that the ethanol sensitive of α-Fe 2 O 3 nanotubes is improved remarkably by doping Pr. Moreover, Pr-doped α-Fe 2 O 3 nanotubes show good selectivity and long-term stability.
研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2021
·
IF 4.527
Lingfang Zou,Zhuan Li,Zonglong Gao,Fu Chen,Wenjie Li,Yong Yu,Yimin Li,Peng Xiao
Improving the piezoelectric activity of lead zirconate titanate (PZT) ceramics is of great importance for practical applications. In this study, the influence of Pr 3+ doping on the ferroelectric phase composition, microstructure, and electric properties on the A-site of (Pb 1-1.5x Pr x )(Zr 0.52 Ti 0.48 )O 3 is extensively investigated. A dense and fine microstructural sample is obtained with the introduction of Pr 3+ . The results show that the morphotropic phase boundary (MPB) moves to the rhombohedral phase region. The rhombohedral and tetragonal phases exhibit an ideal coexistence in the 4 mol.% Pr 3+ doped (PPZT4) samples. Lead vacancy and the reduction of the potential energy barrier are considered to be the key mechanisms for donor doping, which is upheld by the Pr 3+ doping. Combining the I-E hysteresis loops with the P-E hysteresis loops, it becomes apparent that both contribution maximums of the domain switching and residual polarisation are in PPZT4. Moreover, the thermal aging resistance of PZT is improved by doping, and the temperature stability is optimised from 83% in PZT to 96% in PPZT4. Hence, an appropriate amount of Pr 3+ doping can effectively improve the piezoelectric activity of PZT ceramics in the MPB area and optimise the performance stability of the material under application temperatures.
研究领域:
材料科学
·
电子工程
✓ 已验证
DOI
高影响因子
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
·
2018
·
IF 3.794
Ting Chen,Jianrui Zha,Xiaojun Zhang,Xiaobo Hu,Weihui Jiang,Zhixiang Xie,Wan Jiang
Yellow inorganic pigments Pr x Zr 1-x SiO 4 (x = 0–0.08) have been prepared by a novel non-hydrolytic sol-gel (NHSG) method at 750 °C for 2 h. Replacing Pr 4+ for Zr 4+ in ZrSiO 4 increased the cell volume and changed the color from white to yellow gradually. The Si―O―Zr and Si―O―Pr bands were observed in the FT-IR spectra of xerogel , indicating it could reach homogeneous mixing at the atomic level. Therefore, it promoted the solid solution reaction between Pr and zircon at low temperature. The samples exhibit high doping limitation (x = 0.08) and brilliant yellow hue ( b * = 69.48) in contrast with the previously reported praseodymium zircon yellow pigments. The intense of yellow hue was increased with increasing the Pr doping content due to the increase of Pr 4+ /Pr 3+ species. After applying on bisque ceramic tiles, the pigment exhibited excellent coloration, high thermal stability and low solubility in molten glazes, indicating its potential application in ceramic decoration.
研究领域:
材料科学
·
无机化学
✓ 已验证
产品关联
DOI
高影响因子
ACS Applied Electronic Materials
·
2021
·
IF 3.314
Xianghua Wang,Zhiliang Xu,Shaoqi Zhuo,Peng Hu,Yong Yang,Bin Zhou,Wen-Hua Zhang
High performance CsPbBr3 nanocrystals (NCs) were synthesized via a hot injection method followed by a room-temperature ligand exchange modification using 3-mercaptopropyltrimethoxysilane (MPTMS). The ligand exchange promotes crystal growth and enhances the photoluminescence quantum yield (PLQY) of the NCs to near unity. The oscillator strength of the interband transition based on UV–vis absorption was surprisingly amplified by a factor of 2.5. The NC’s surface was passivated via S–Pb polar covalent bonding, which shifts the thermodynamic equilibrium and favors NC growth with a higher Br-to-Pb atomic ratio on the surface. Moreover, the perovskite lattice was strained by a cross-linked polymeric network of self-condensed siloxane. The strain within CsPbBr3 NCs was modulated by mixing at room temperature with Cs3PrCl6 NCs for controlled halide exchange and Pr doping; thereby blue emission from the Pr-doped CsPb(Cl/Br)3 NCs was achieved with optimized brightness (PLQY = 88%) at 464 nm.
研究领域:
材料科学
·
光学
✓ 已验证
产品关联
DOI
高影响因子
Journal of Energy Chemistry
·
2024
·
IF 14
Botao Fan,Hao Zhang,Bang Gu,Feng Qiu,Qiue Cao,Wenhao Fang
Electrocatalytic conversion of renewable biomass is emerging as a promising route for sustainable chemical production; hence it urgently calls for developing efficient electrocatalysts with low potentials and high current densities. Herein, a Pr-doped Co(OH) 2 hexagonal sheet (Pr/Co = 1/9, in mole) is synthesized by electrodeposition as highly performant catalyst for 5-hydroxymethylfurfural (HMF) oxidation reaction (HMFOR) to produce 2,5-furandicarboxylic acid (FDCA). This novel and low-cost catalyst possesses a rather low onset potential of 1.05 V (vs. RHE) and requires only 1.10 V (vs. RHE) to reach a current density of 10 mA cm −2 for HMFOR, significantly outperforming Co(OH) 2 benchmark (i.e., 210 mV higher to reach 10 mA cm −2 ). The origin of Pr promotion effect as well as the evolution of CoOOH catalytic sites and HMFOR process has been deeply elucidated by physical characterizations, kinetic experiments, in situ electrochemical techniques, and theoretical calculations. The unique Pr-ameliorated CoOOH active centers enable 100% conversion of HMF, 99.6% selectivity of FDCA, and 99.7% Faraday efficiency, with a superior cycling durability toward HMFOR. This can be one of the most outstanding results for Co-based HMFOR catalysts to date in the literature. Thereby this work can help open up new horizons for constructing novel and efficient Co-based electrocatalysts by the utilization of lanthanide elements.
研究领域:
材料科学
·
电化学
·
催化化学
✓ 已验证
产品关联
DOI
高影响因子
Journal of Materials Chemistry C
·
2024
·Vol. 12
·期 28
·10513-10531
·
IF 5.7
Xiaoqiang Xiong,Xiaodong Jing,Zitao Chen,Qianqian Zhao,Zuoguang Li,Xi Yang,Qun Wang,Tongyun Zhao,Huayang Gong
Using single loss type media as microwave absorbers to simultaneously achieve low reflection loss, wide-band absorption and thin thickness is a huge challenge. In this work, to combine the high dielectric loss of Pr-doped M-type strontium ferrite and the high magnetic loss of W-type hexaferrites, we improved the traditional sol–gel auto-combustion method via increasing an extra sintering process and successfully prepared xSrPr0.5Fe11.5O19/yBaCo2Pr0.5Fe15.5O27 (x : y = 2 : 1, 1.5 : 1, 1 : 1, 1 : 1.5 and 1 : 2) M/W (M-type hexaferrite/W-type hexaferrite) composite materials with a unique “inlay structure”. The M-phase and PrFeO3-type phase were partially wrapped by the huge W-phase, which resulted in enhanced exchange coupling. Benefitting from the exchange coupling and huge grains, the coercivity and anisotropy fields of composite hexaferrites decreased. Therefore, the natural resonance frequencies of some samples reduced to within 18.00 GHz. High magnetic loss occurs while dielectric loss is preserved due to strong resonance interaction and multiple polarization relaxation mechanisms. Hence, the composite hexaferrites exhibit satisfactory microwave absorption performance on account of the magnetic–dielectric synergistic effect. The effective absorption bandwidth of the prepared materials can cover X and Ku bands at thin matching thicknesses (<2.00 mm). The minimum reflection loss reaches −56.30 dB (d = 1.97 mm), and the maximum effective absorption bandwidth reaches 8.17 GHz (d = 1.63 mm). This work will provide new ideas for improving the absorption performance of ferrite composite materials.
研究领域:
材料科学
·
电磁学
✓ 已验证
DOI
高影响因子
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