Synthesis of PtxSn/MWCNTs and their Application in Non-enzymatic Glucose and Hydrogen Peroxide Sensors
Pt x Sn/MWCNTs (x=1, 2, 3) nanocomposites were synthesized by chemical reduction. Comparing all of the materials, the results revealed that the best material was Pt 3 Sn/MWCNTs. The sensor based on Pt 3 Sn/MWCNTs exhibited excellent catalytic activities towards glucose and hydrogen peroxide. Sensing of glucose had a double-linear range: one was between 50 μM and 550 μM, the other was between 1.35 mM and 16.35 mM. These were due to the fact that more and more intermediate species were adsorbed onto the electrode surface with increasing concentration of glucose, which limited the following glucose oxidation. Meanwhile, the sensor also had a linear response range between 0.05 mM and 18.95 mM for hydrogen peroxide. Furthermore, the glucose and hydrogen peroxide sensors exhibited excellent selectivity, stability, and reproducibility. Thus the sensors had potential utilities in the detection of glucose and hydrogen peroxide.
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