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Sodium Bis(acyl)phosphane oxide (SBAPO): An efficient photoinitiator for blue light initiated aqueous RAFT dispersion polymerization

Jun He,Dongdong Liu,Jianbo Tan,Li Zhang

We report a novel blue light initiated aqueous reversible addition–fragmentation chain transfer (RAFT) dispersion polymerization of 2-hydroxypropyl methacrylate (HPMA) with a poly (glycerol monomethacrylate) homopolymer as the macro-RAFT agent and sodium bis(acyl)phosphane oxide (SBAPO) as the photoinitiator . High monomer conversions were achieved within 1 h of blue light irradiation . Taking advantage of the temperature-insensitive feature of photoinitiator , the effect of reaction temperature on the blue light initiated aqueous RAFT dispersion polymerization was studied in detail. A new morphological phase diagram was constructed for the first time by changing the degree of polymerization (DP) of the core-forming block and the reaction temperature. Moreover, a typical morphological phase diagram for the blue light initiated aqueous RAFT dispersion polymerization at 70 °C was also built and various morphologies have been prepared. Effect of wavelength of light (405 and 465 nm) on copolymer compositions and morphologies was studied. Finally, a fully one-pot blue light initiated aqueous RAFT polymerization was developed for the synthesis of various diblock copolymer nano-objects.