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PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS · 2025 · IF 1

Enhancing Hastelloy tape surfaces flattening efficiency via autonomously designed SDP system derived Y2O3 coatings

Mingyuan Zhao,Bowan Tao,Ruipeng Zhao,Xi Chen,Zhenzhe Li,Tian Xie,Qichen Wang,Silong Fang,Ziwen Jin,Yudong Xia

The widespread application of second-generation high-temperature superconducting (2G HTS) tapes has elevated demand for surface smoothing of long-length Hastelloy tapes utilizing simple and low-cost strategies. Amorphous Y 2 O 3 has been used to flatten the long-length Hastelloy tape surfaces via solution deposition planarization (SDP). In this work, the autonomously designed SDP system is applied to flatten the Hastelloy surface while significantly increasing progress rate. As a result, lifting speed up to 75 m/h, while the root mean square (RMS) roughness on Hastelloy tape surfaces was reduced from 28.13 nm to 0.76 nm over 5 × 5 μm² areas. These are superior to those of the state-of-the-art SDP lifting speeds. Additionally, the surface flattening process was elaborated through power spectral density (PSD). The Hastelloy tape surfaces have been confirmed to form a well-biaxially textured MgO buffer layer. The autonomously designed SDP system shed light on an effective strategy for flattening long-length Hastelloy tape surfaces.

CAS / MDL: 102-71-6 112-24-3
研究领域: 材料科学 · 表面工程
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Energies · 2024 ·Vol. 18 ·期 1 ·61 · IF 3

Research on the Application Potential of New Nano-Oil Displacement Agents to Improve Shale Oil Recovery Rates

Haibo He,Jixiang Guo,Bo Wang,Yuzhi Zhang,Fan Lei,Tao Wang,Tiantian Zhang,Jing Wang

To meet the demand for enhanced oil recovery in shale reservoirs and to improve the fluidity of shale oil while strengthening its imbibition effect, a multifunctional, thermally stable nanofluid agent, SDP-3, was synthesized using acrylamide (AM) and 2-acrylamido-2-methylpropanesulfonicacid (AMPS) as the primary raw materials. A series of characterizations and tests were conducted to evaluate its interfacial properties, stability, viscosity reduction performance, wettability, and imbibition-driven oil recovery capabilities. Furthermore, the mechanisms by which SDP-3 enhances the recovery of shale oil were analyzed. The results demonstrated that a mass concentration of 2% SDP-3 could reduce the oil–water interfacial tension to 0.071 mN/m. When the concentration increased to 2.0%, the interfacial tension further decreased to 0.071 mN/m, at which point the viscosity reduction rate for shale oil reached 92.02%, and the imbibition recovery rate was 36.57%. Microscopic observations revealed that SDP-3 could disperse shale oil into fibrous and spherical forms, effectively detaching the adhering shale oil from minute pores. This nanofluid agent not only exhibits excellent compatibility and stability but also achieves an ideal oil recovery effect while significantly improving recovery rates, showcasing its immense application potential in oilfield development.

研究领域: 石油工程 · 材料科学 · 化学工程
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JOURNAL OF THE AMERICAN CERAMIC SOCIETY · 2018 ·Vol. 102 ·期 5 ·2415-2425 · IF 2.956

Surface engineering of the flexible metallic substrate by SDP-Gd-Zr-O layer for IBAD-MgO templates

Jingyuan Chu,Yue Zhao,Guangyu Jiang,Wei Wu,Zhiwei Zhang,Zhiyong Hong,Zhijian Jin

Tuning substrate properties is an effective methodology to modulate the texture development of MgO films deposited by ion beam-assisted deposition (IBAD) process for epitaxial oxide films. Herein, a solution deposition planarization (SDP) technique is employed to deposit Gd-Zr-O layer for engineering surface properties of the flexible metal substrate. The correlation between the Gd-Zr-O thin film microstructure and the IBAD-MgO texture is investigated. The coordinated study on atomic force microscopy (AFM) and reflection high-energy electron diffraction (RHEED) reveal that the grain coarsening during high-temperature sintering negatively influences the texture formation of IBAD-MgO. Moreover, the chemical environment of the atoms on the surface of Gd-Zr-O seed layer also plays a critical role, which is normally overlooked. The X-ray photoelectron spectroscopy (XPS) analysis indicates that the carbon residue and intermediate phase result in the poor texture of the IBAD-MgO. This phenomenon is related to the partial decomposition and synthesis reactions due to the lower sintering temperature or reduced surface to volume ratio. We demonstrate the high-quality texture of IBAD-MgO layer, deposited on mono-coated thick Gd-Zr-O film, by using optimal heat-treatment conditions. The cross-sectional TEM images present the dense Gd-Zr-O film with Gd 2 Zr 2 O 7 nanograins. The multifunctionalities, such as planarization, a barrier layer, and seed layer, of Gd-Zr-O layers are realized in full-stacked CeO 2 /LaMnO 3 /IBAD-MgO/SDP-Gd-Zr-O/C276 samples. This work demonstrates a route for simplifying the architecture of 2G-HTS using Gd-Zr-O layer and explores the effect of the surface properties on texture formation in IBAD-MgO layer.

CAS / MDL: 17501-44-9
研究领域: 材料科学 · 物理学
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JOURNAL OF COLLOID AND INTERFACE SCIENCE · 2024 · IF 9.4

A primitive cell model involving Vesicles, microtubules and asters

Dong Guo,Ziyue Zhang,Jichao Sun,Wanguo Hou,Na Du

Hypothesis Simple single-chain amphiphiles (sodium monododecyl phosphate, SDP) and organic small molecules (isopentenol, IPN), both of primitive relevance, are proved to have been the building blocks of protocells on the early Earth. How do SDP-based membrane and coexisting IPN come together in specific ways to produce more complex chemical entities? What kind of cell-like behavior can be endowed with this protocell model? These are important questions in the pre-life chemical origin scenario that have not been answered to date. Experiments The phase behavior and formation mechanism of the aggregates for SDP/IPN/H 2 O ternary system were characterized and studied by different electron microscopy, fluorescent probe technology, DLS, IR, ESI-MS, SAXS, etc. The stability (freeze–thaw and wet-dry treatments) and cell-like behavior (chemical signaling communication) were tested via simulating particular scenarios. Findings Vesicles, microtubules and asters phases resembling the morphology and structure of modern cells/organelles were obtained. The intermolecular hydrogen bonding is the main driving force for the emergence of the aggregates. The protocell models not only display remarkable stabilities by simulating the primordial Earth’s diurnal temperature differences and ocean tides but also are able to exhibit cell-like behavior of chemical signaling transition.

研究领域: 前生物化学 · 生命起源 · 软物质物理 · 生物物理学
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Materials Science & Engineering C-Materials for Biological Applications · 2020 · IF 5.88

Self-assembled multifunctional nanotheranostics loading GEM for targeted lung cancer therapy

Jun Tang,Fushuang Zheng,Jungang Zhao,Jianzhu Zhao

The aim of this study was to prepare a promising drug carrier for treatment of lung cancer. The self-assembly nanoparticles of SDP-GEM/PEI-PEG-anti-EGFR with chemotherapeutic drug of gemcitabine (GEM), Magnetic resonance imaging (MRI) guided- imaging and targeting of anti- Epidermal Growth Factor Receptor (anti-EGFR) were designed. The imaging capacity, targeting feasibility and anti-tumor function were evaluated respectively. SDP-GEM/PEI-PEG-anti-EGFR exhibited contrast enhancement under T2 Weight Image (T2WI) and a liner relationship was found between the concentration and relaxation rate of R2 and R2* in vitro . With the targeting of anti-EGFR, the endocytosis of nanoparticles increased significantly, which effectively killed lung cancer cells in vitro , and importantly it can be accurately delivered to tumor site within 3 h in vivo . Prolonged lifetime and smaller tumor volume demonstrated that SDP-GEM/PEI-PEG-anti-EGFR efficiently inhibited tumor growth in vivo . Therefore, SDP-GEM/PEI-PEG-anti-EGFR was an effective and safe drug carrier, which had a great potential application in MRI-guided lung cancer therapy.

研究领域: 纳米技术 · 癌症治疗 · 分子影像 · 药物递送系统
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