Enhancing electromagnetic wave absorption with core-shell structured SiO2@MXene@MoS2 nanospheres
Material composition and structural design are important factors influencing the electromagnetic wave (EMW) absorption performance of materials. To alleviate the impedance mismatch attributed to the high dielectric constant of Ti 3 C 2 T x MXene, we have successfully synthesized core-shell structured SiO 2 @MXene@MoS 2 nanospheres. This architecture, comprising SiO 2 as the core, MXene as the intermediate layer, and MoS 2 as the outer shell, is achieved through an electrostatic self-assembly method combined with a hydrothermal process. This complex core-shell structure not only provides a variety of loss mechanisms that effectively dissipate electromagnetic energy but also prevents self-aggregation of MXene and MoS 2 nanosheets. Notably, the synergistic combination of SiO 2 and MoS 2 with highly conductive MXene enables the suitable dielectric constant of the composites, ensuring optimal impedance matching. Therefore, the core-shell structured SiO 2 @MXene@MoS 2 nanospheres exhibit excellent EMW absorption performance, featuring a remarkable minimum reflection loss (RL min ) of −52.11 dB (2.4 mm). It is noteworthy that these nanospheres achieve an ultra-wide effective absorption bandwidth (EAB) of 6.72 GHz. This work provides a novel approach for designing and synthesizing high-performance EMW absorbers characterized by “wide bandwidth and strong reflection loss.”
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