ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
·
2024
·
IF 1.1
Ting Chen,Hanzi Du,Ralf Riedel,Zhaoju Yu
This work successfully fabricated a novel CNWs/Ni 2 Si/SiOC nanocomposite ceramic material using a single-source-precursor derived ceramic approach. The material exhibits in-situ formation of carbon nanowires (CNWs) and multiple core-shell nanoparticles such as Ni 2 Si@C and SiC@C. The reaction mechanism of the precursor, the microstructure and phase composition, and the ceramics′ electromagnetic wave (EMW) absorbing properties were thoroughly investigated and discussed. The obtained CNWs/Ni 2 Si/SiOC nanocomposite ceramics possesses a minimum reflection loss (RLmin) of −43.5 dB, indicating excellent EMW absorbing performance. The in-situ formation of CNWs and multi-core-shell nanoparticles (Ni 2 Si@C and SiC@C) in the ceramics play a crucial role in enhancing their EMW absorbing properties compared to pure SiOC ceramics.
研究领域:
材料科学
·
电磁学
✓ 已验证
产品关联
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2023
·
IF 5.2
Hongmei Chen,Shu Yu,Yunping Li
SiOC and SiCaMgOC coatings were prepared by sol–gel method from precursors of hydrosilane and the mixture of hydrosilane, calcium acetylacetonate (Ca(acac) 2 ) and magnesium acetylacetonate (Mg(acac) 2 ), respectively. Fourier transform infra-red (FTIR) and X-ray photoelectron spectroscopy (XPS) analysis on the coatings revealed that Ca 2+ and Mg 2+ ions can be successfully doped into SiOC coating after aging and annealing in the SiCaMgOC coating. The cytotoxicity and bioactivity of three samples have been detected by MTT assay, cell adhesion and simulated boy fluid (SBF) immersion test. The results suggested that SiCaMgOC coating induced more apatite than that of C/C and SiOC in the comparable soaking process. SiCaMgOC coating demonstrated better biological activity and cellular adherence for its higher surface roughness and ion exchange reaction between Ca 2+ and Mg 2+ ions and protons (H + /H 3 O + ) in the SBF solution.
研究领域:
材料科学与工程
·
生物医学工程
✓ 已验证
产品关联
DOI
高影响因子
CARBON
·
2022
·
IF 11.307
Shixiang Zhou,Li Yao,Tong Zhao,Hui Mei,Konstantinos G. Dassios,Laifei Cheng,Litong Zhang
Chemiresistive SiOC Negative Poisson's ratio structures for gas detection under thermal and pressure loading were constructed by vat photopolymerization and surface sensitization. Metal-organic framework-derived SnO 2 nanocubes modification provided the structures with sensing capability, while the high deformation-resistant SiOC substrates protected the integrity and connectivity of the sensing layer. The resulting SnO 2 /SiOC sensing structures exhibited high selectivity to formaldehyde vapor and showed a response value of 3.6 to 100 ppm formaldehyde vapor. The structures also had a short sensing delay with the response and recovery times of 32 s and 41 s, respectively. Besides, the independent deformation of the units maintained the dimensional accuracy and avoided thermal fatigue failure of the structure at the working temperature by dispersing the thermal stress, at which the coefficient of thermal expansion reached 0.71 × 10 −6 /K, revealing a near-zero expansion behavior. Meanwhile, the mechanical performance can be adjusted by structure optimization, and the compressive strength and Young's modulus of the structure reached 51.25 MPa and 5.14 GPa, respectively. Taking advantage of the strengthened and self-adaptive design, the structure exhibited high load-carrying capacity and low thermal expansion performance, providing a facile strategy for highly stable gas detection under complex loading environments.
研究领域:
材料科学
·
传感器技术
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
APPLIED SURFACE SCIENCE
·
2020
·
IF 6.182
Jianmei Pan,Wei Shen,Yahai Zhang,Hua Tang,Haoyu Sun,Wenqiang Zhong,Xuehua Yan
Photocatalytic water splitting to product hydrogen (H 2 ) is a desired route to utilize solar energy into chemical energy. At present, most photocatalysts for H 2 generation contains metallic elements with high-cost, confined reserves, and environmentally unfriendly. The exploitation of metal-free and efficient photocatalysts becomes particularly important. Herein, a new metal-free g-C 3 N 4 -based heterojunction composites were facilely produced via the ultrasonic assisted deposition and subsequent calcination from g-C 3 N 4 layers embedded with SiOC with prominent conductivity and large surface area. Systematic investigates suggested that the SiOC/g-C 3 N 4 heterojunctions exhibited eminently meliorated photocatalytic H 2 production efficiency. The optimum H 2 production rate (1020 μmol h −1 g −1 ) of the SiOC/g-C 3 N 4 photocatalyst is 3.2 and 25.5 folds that of g-C 3 N 4 and SiOC , respectively. The boosted photocatalytic activity primarily originates from the increased absorptivity of light, the markedly expedited charge migration and the impeded recombination of charge carriers. This study offers a new perspective for the scientific contrive and fabrication of high-quality heterojunction photocatalysts for solar energy utilization.
研究领域:
材料科学
·
能源科学
✓ 已验证
DOI
高影响因子
COMPOSITES PART B-ENGINEERING
·
2021
·
IF 9.078
Shixiang Zhou,Li Yao,Hui Mei,Mingyang Lu,Laifei Cheng,Litong Zhang
As the operation reliability for gas sensors under complex environments is in increasing demand, the stability and safety performance are significant besides qualified gas sensing properties. In this work, structural-strengthened and self-protective ammonia sensing micro-tunnels were constructed by 3D printing . Modified methyl-silsesquioxane (MK) resin was employed as the feedstock to build the SiOC honeycomb structures . Polypyrrole (PPy) nanoparticle decorated TiO 2 arrays sensitized the structures to form inner gas-sensitive tunnels . The sensing structure exhibited high selectivity toward ammonia at room temperature. Response to 50 ppm NH 3 was 18.67%, while the response and recovery times were 119 and 86 s, respectively. The excellent long-term stability also ensured reliable operation in complex environments. More importantly, the enhanced honeycomb had an outstanding mechanical performance with the compressive strength , Young's modulus , and energy absorption of 33.72 MPa, 2.40 GPa, and 28.22 kJ/m 3 , respectively. It can serve as a load-bearing part of the fundamental component to avoid catastrophic collapse while maintaining a regular sensing capability under pressure loading as the excellent deformation resistance ensured the integrity and connection of the sensing layer. Moreover, the inner through-holes facilitated the exposure of the sensing tunnels to the atmosphere, which can detect target gas simultaneously without the embedding of extra sensors. Thus, the construction of self-protective gas sensing structures was promising to be an efficient strategy for reliable gas detection in extreme environments.
研究领域:
材料科学
·
传感器技术
✓ 已验证
DOI
高影响因子
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
·
2025
·
IF 3.8
Yiran Liu,Yimin Ouyang,Linwei Guo,Saidi Wang,Yihui Yang,Bin Du,Tao Zhang
Polymer-derived SiOC ceramics have demonstrated significant potential across various applications, including structure materials, energy, extreme thermal environments, and semiconductors. It is well-established that the carbon phase in SiOC plays a crucial role in determining the material's properties. However, the relationship between carbon phases and the mechanical properties of SiOC ceramics remains inadequately explored. In this study, a series of SiOC nanosphere powders with varying carbon content were successfully fabricated, and bulk samples were obtained using the spark plasma sintering (SPS) technique. The results demonstrate that both carbon content and sintering temperature play a synergistic role in determining the phase composition—such as the formation of SiC through carbothermal reduction—and the microstructural features, including densification and the distribution of free carbon in SiOC ceramics. These structural modifications significantly enhance the mechanical properties through multiple mechanisms. Among all the samples, the SiOC-C ceramics fabricated at 1600°C possess optimized mechanical properties, with a flexural strength of 38.48 MPa. These findings elucidate the potential mechanism for improving the mechanical properties of SiOC ceramics by introducing the carbon phase, which holds significant implications for the development of high-performance ceramic materials.
研究领域:
材料科学
·
机械工程
✓ 已验证
产品关联
DOI
高影响因子
APPLIED SURFACE SCIENCE
·
2024
·
IF 6.3
Yun-Yang Li,Hao-Jie Yan,Ruo-Zhan Yin,Qing-Qing Sun,Lian-Kui Wu,Fa-He Cao
In this work, SiOC coatings incorporated with Ni nanoparticles were fabricated on γ-TiAl alloy by dip-coating. The microstructure and high temperature oxidation behavior of the SiOC-Ni coatings with different Ni contents were investigated. Results showed that the incorporation of Ni nanoparticles improved the oxidation resistance of the SiOC coating at 850 ℃. During thermal exposure to air, the incorporated Ni particles would react with both oxygen and the SiOC coating, forming NiO and Ni 2 Si, respectively, therefore changing the structure of the SiOC coating. The generation of NiO and Ni 2 Si is beneficial in reducing the oxygen partial pressure at the coating/substrate interface, thereby facilitating the formation of a protective aluminum oxide layer.
研究领域:
材料科学
·
表面工程
✓ 已验证
产品关联
DOI
高影响因子
International Journal of Applied Ceramic Technology
·
2021
·Vol. 19
·期 2
·813-827
·
IF 1.968
Cong Zhou,Shuang Li,Zhaoju Yu
Iron-containing PSO precursors (FePSO) were synthesized by modification of polysiloxane with different amounts of ferric acetylacetonate [Fe(acac) 3 ], then porous SiFeCO ceramics were successfully prepared by subsequent pyrolysis. The chemical modification and ceramization process of PFSO precursors were studied by FT-IR and TGA measurements. XRD patterns imply that the SiC crystalline can be easily observed when PFSO was exposed to 1200℃ in nitrogen atmosphere, while pure PSO exhibited broad diffraction peaks of SiC at 1500℃, meaning that the grain coarsening of SiC was accelerated by adding iron. The crystallization behavior of ferric silicide (Fe x Si y ) is complex due to the variation of iron content in feed and annealing temperature, and Fe x Si y /SiC@SiOC nanocomposites were produced after annealing. Because of the in-situ formation of SiC, Fe x Si y , and carbon strips in nanocomposites, PFSO-derived ceramics demonstrate enhanced microwave absorption performance. The best effective absorption bandwidth (<−10 dB) and the minimum reflection loss are 2.6 GHz and −38 dB, respectively, which are achieved in the sample PFSO-3–1300℃. Fe x Si y /SiC@SiOC nanocomposites synthesized in this work exhibit potential application in the field of electromagnetic interference, the carbon content and the crystallization behavior of Fe x Si y are the critical factors for the performance optimization.
研究领域:
材料科学
·
电磁学
✓ 已验证
产品关联
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2024
·
IF 13.3
Ruyue Su,Jingyi Chen,Xueqin Zhang,Wenqing Wang,Rujie He,Hao Xu,Ying Li
Electromagnetic interference (EMI) shielding and absorption materials can effectively mitigate the undesired pollution or noise caused by terahertz (THz) waves. The development of THz EMI shielding materials that are primarily based on absorption mechanisms to avoid secondary pollution caused by reflection is still in big demand. Herein, an absorption-dominated precursor-derived SiOC ceramic (PDC-SiOC) architecture for THz wave EMI shielding and absorption was reported. The EMI shielding properties of the bulk SiOC ceramic were studied. More than 93 % of THz EM waves were absorbed by the synthesized SiOC ceramic from 1.2 to 1.6 THz. Furthermore, lightweight honeycomb-structured SiOC architecture which was inspired by the wings of moth was fabricated by vat photopolymerization 3D printing combined with following pyrolysis. The EMI shielding properties and mechanism of the honeycomb SiOC architecture in THz bands were also discussed. The highest shielding effectiveness (SE) of the honeycomb SiOC architecture was up to 64.1 dB, and the transmissivity was below 1.4 % from 0.2 to 1.6 THz. In addition, more than 97–99.8 % of THz waves were absorbed in 0.8–1.6 THz. The excellent EMI shielding performance of the architecture was mainly attributed to its outstanding THz EM wave absorption ability. Finally, the mechanical properties and thermal stability of the architecture were further studied. The compressive and flexural strength of honeycomb architecture was 1.2 and 16.5 MPa, respectively. The result also proved that the honeycomb SiOC architecture was resistant to high temperatures up to 1100 °C under inert atmosphere. This work provides promising high-efficiency architecture towards THz EMI shielding and absorption.
研究领域:
材料科学
·
电磁学
✓ 已验证
产品关联
DOI
高影响因子
RSC Advances
·
2015
·Vol. 5
·期 66
·53441-53447
·
IF 3.84
Jia Ma,Yunlong Ning,Cairong Gong,Gang Xue,Guoliang Fan
Three-dimensionally ordered macroporous (3DOM) SiOC was successfully fabricated on a cordierite monolith inner wall of a polystyrene (PS) sphere template through a colloidal crystal templating (CCT) method (named as 3DOM SiOC/cordierite). And perovskite-type LaCoO3 (LCO) mixed metal oxides, prepared by a facile sol–gel process, were coated onto the wall of the 3DOM SiOC/cordierite by a simple impregnation-sintering approach (named as LCO/3DOM SiOC/cordierite). The morphological and physicochemical properties studies indicate that the 3DOM structure has excellent connectivity, a large specific surface area, and applicable pore size. And the 3DOM structure plays an important role in preventing aggregation of the targeted catalyst particles, improving the contact condition between catalysts and soot as well as enhancing the reducibility of the LCO. The subsequent investigation on the catalytic performance of the 3DOM samples for diesel soot combustion shows that the 3DOM texture offers the catalyst a lower soot combustion temperature than a conventional catalyst, and the LCO/3DOM SiOC/cordierite reduces the combustion temperature even further while avoiding the rise of back-pressure effectively as well.
研究领域:
材料科学
·
环境工程
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
·
2018
·Vol. 101
·期 10
·4763-4772
·
IF 2.956
Nan Wu,Bing Wang,Yingde Wang
Flexible ceramic nanofibers are highly desired due to their potential applications in free-standing catalyst supports, fine particulate filters and flexible electronic devices. In this work, robust SiOC fibrous membranes composed of randomly oriented nanofibers with an average diameter of 550 nm were fabricated by a combination of electrospinning and post heat-treatment process. The mechanical properties of the as-prepared membranes were enhanced significantly through in situ embedding of palladium nanoparticles into the SiOC fibers. The optimized palladium-doped SiOC fibrous membrane demonstrated a low flexural modulus of 7.79 kPa and a high tensile strength of 33.2 MPa. Reduced flaw size, initiation of nanocracks and pinning effect were proposed to explain the enhancement mechanism. Furthermore, the flexible SiOC membrane with excellent corrosion resistance exhibits a high filtration efficiency of 99.6% when the membrane weight is 4.8 g m −2 , suggesting efficient filtration applications in harsh environments. This work also provides a feasible strategy for the design and fabrication of the flexible amorphous ceramic fiber membranes for various applications.
研究领域:
材料科学
·
纳米技术
✓ 已验证
产品关联
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2024
·
IF 5.1
Jiale Liu,Zahoor Ahmad,Jianjun Chen
The continuous SiOC ceramic fibers were fabricated by a novel polyethylene oxide (PEO) assisted sol-gel method. The precursor fibers were prepared by a solution which viscosity and composition can be regulated. The solution with excellent spinning performance was constituted by the optimized composition of tetraethyl orthosilicate, methyltrimethoxysilane, sucrose, and PEO. The effects of the pyrolysis temperatures and C/Si ratios on the microstructure and mechanical properties of SiOC ceramic fibers were investigated. After pyrolysis at 1200 °C, the tensile strength of SiOC ceramic fibers was 182.5 MPa and the surface was uniform and dense. Furthermore, XPS and FTIR analysis confirmed the formation of Si–O–Si and Si–C bonds, demonstrating the existence of SiO 3 C after pyrolysis at 1200 °C. The oxidation and high-temperature resistance of the SiOC ceramic fibers were also investigated. The results showed their ability to withstand heat treatment at 1000 °C in air and 1200 °C in Ar. The continuous SiOC ceramic fibers have broad prospects for commercial application as the thermal protection and high temperature resistant material. And the novel PEO-assisted sol-gel method can be employed to fabricate various ceramic fibers.
研究领域:
材料科学
·
陶瓷工程
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）