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SnO2\CdSe/Bi2O3
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY · 2018 · IF 4.841

Preparation of ortho-symmetric double (OSD) Z-scheme SnO2\CdSe/Bi2O3 sonocatalyst by ultrasonic-assisted isoelectric point method for effective degradation of organic pollutants

Siyi Li,Meng Zhang,Xue Ma,Jing Qiao,Hongbo Zhang,Jun Wang,Youtao Song

In this work, an ortho-symmetric double (OSD) Z-scheme SnO 2 \CdSe/Bi 2 O 3 sonocatalyst is skillfully designed and synthesized via ultrasonic-assisted isoelectric point method and then the sonocatalytic activity is studied under ultrasonic irradiation in the degradation of organic contaminants. The effects of ultrasonic irradiation time, sonocatalyst dosage, initial Rhodamine B concentration, organic dye kind and used times are investigated systemically. The formation of OH and h + are confirmed by using t-BuOH and oxalate, respectively. The Rhodamine B can completely be degraded under given experimental conditions such as 10   mg/L Rhodamine B solution, 1.00   g/L OSD Z-scheme SnO 2 \CdSe/Bi 2 O 3 dosage and 150   min ultrasonic process. The formation of mainly intermediate products is studied by Liquid Chromatography–Mass Spectrometry. Moreover, the sonocatalytic reaction mechanism caused by OSD Z-scheme SnO 2 \CdSe/Bi 2 O 3 is presented.

研究领域: 环境科学 · 材料科学
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