High stability cubic perovskite Sr0.9Y0.1Co1-xFexO3-δ oxygen evolution by phase control and electrochemical reconstruction
Transition metal oxides are considered ideal electrocatalyst materials due to their low cost and high intrinsic activity. Among them, SrCoO 3- δ has received increasing attention due to its multi-phase structure and tunable electronic properties, though its OER reaction kinetics and catalysis stability are unsatisfactory. Herein, based on a simple one-step solid-state reaction method, we use a small amount of rare earth Y ions (10 %) to transform H-SCO 2.52 from a hexagonal structure to a stable cubic perovskite Sr 0.9 Y 0.1 CoO 3− δ . While broadening the atomic ratio of Co and Fe in the B-site under the cubic perovskite Sr 0.9 Y 0.1 Co 1- x Fe x O 3− δ ( x = 0–1), the relationship between the B-site electronic state, oxygen vacancies, and OER performance has been explored. Sr 0.9 Y 0.1 Co 0.2 Fe 0.8 O 3− δ with a high concentration of oxygen vacancies, exhibits the lowest overpotential of 277 mV and maintains stability at 10 mA cm −2 for 88 h. The valence states of Fe and Co atoms in SYC0.2F0.8 O are optimized (Fe 2+ ∼50.81 %, Co 2+ ∼19.39 %), and the oxygen evolution activity is enhanced by electrochemical reconfiguration to form high-valence Fe and Co ions. Selective leaching of Sr ions via electrochemical surface reconstruction activates FeOOH and CoOOH amorphous layer active sites on the catalyst surface, significantly enhancing reaction kinetics.
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