Phase Structures and Dielectric Properties of (n + 1)SrO − nCeO2 (n = 2) Microwave Ceramic Systems with TiO2 Addition
Ti4+-ion-doped (n+ 1)SrO −nCeO2(n= 2) ceramic systems were prepared with the conventional solid-state reaction method, and the effects of the phase structures and compositions, sintering behaviors, microstructures and microwave dielectric properties of these ceramic systems were investigated in detail as a function of TiO2content. The analytical results of the XRD patterns show that the pure (n+ 1)SrO −nCeO2(n= 2) system is a composite-phase ceramic system with coexisting SrCeO3and Sr2CeO4phases (represented as a SrCeO3+ Sr2CeO4system), which belong to the orthogonal structures of the Pmcn (62) and Pbam (55) space groups, respectively. For thexTiO2-(1 − x) (SrCeO3+ Sr2CeO4) (x= 0.1–0.4) ceramic samples, the secondary phase Sr2TiO4can also be detected within the range of the investigated components. Meanwhile, the Raman spectroscopy, SEM-EDS, and HRTEM (SAED) analysis results also verified the correctness and consistency of the phase structures and compositions for all the given specimens. In addition, complex impedance spectroscopy was used to detect the conductive behavior of these compound ceramic systems, and the calculation results show that the appropriate addition of Ti4+-ions can make the SrCeO3+ Sr2CeO4system have better thermal stability. The composition ofx= 0.2 multiphase structural ceramic sample sintered at 1330 °C for 4 h has a near zero τfvalue of ~−4.6 ppm/°C, a moderateεrof ~40.3 and a higherQ×f~44,020 GHz (at 6.56 GHz). The relatively superior-performing ceramics developed in this work are expected to provide a promising microwave dielectric material for communication components.Keywords:phase structures and compositions;SrCeO3+ Sr2CeO4system;TiO2addition;microwave dielectric properties
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