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MATERIALS RESEARCH INNOVATIONS · 2023 · IF 0

Facile synthesis of β-cyclodextrin decorated Super P Li carbon black for the electrochemical determination of methyl parathion

Yunhang Liu,Jiale Han,Yurii Mishchenko,Andrii Butenko,Vladyslav Kovalenko,Hongyuan Zhao

Herein, a novel electrochemical sensor was designed for the sensitive determination of methyl parathion (MP) using the Super P Li carbon black@β-cyclodextrin (SPLCB@β-CD) decorated glassy carbon electrode (GCE). SPLCB with high electroactive area exhibited exceptional conductivity and good dispersive property, which is beneficial for forming the interlinked conductive network structure. β-CD could not only promote the uniform dispersion of SPLCB but also effectively realise the enrichment of MP molecules. Moreover, the existence of SPLCB could make up for the defect of poor conductivity of β-CD. Under the optimal experimental condition (pH = 7.0, enrichment time: 60 s). The collaborative cooperation of SPLCB and β-CD achieved the excellent MP detection property (LOD: 8.6 nM; concentration range: 0.01–10 μM). The SPLCB@β-CD/GCE sensor exhibited acceptable repeatability and reproducibility. In addition, the proposed sensor was successfully employed to detect MP in apple juice (Recoveries: 98.0–98.6%, RSD values: 3.68–4.63%).

研究领域: 分析化学 · 环境科学 · 食品科学
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