Plasma electrolytic oxidation (PEO) has demonstrated significant enhancements in the mechanical properties and corrosion resistance of titanium alloys. Despite these advantages, the presence of micropores and microcracks in the coating can still detrimentally impact tribological properties. This paper introduces a novel approach involving the in-situ growth of a surface structure. The resulting interface structure exhibits outstanding tribological properties under a load of 3 N and a speed of 1.5 cm/s. In contrast to prior studies, improvements are made to the electrical parameters and electrolyte formula of Plasma electrolytic oxidation, facilitating the in-situ growth of MoSe 2 . This results in the formation of a lubricating layer and a robust TiO 2 ceramic coating with excellent adhesion. A systematic analysis of friction, wear characteristics, reveals that MoSe 2 in situ grow on the surface of the PEO coating, within micropores, microcracks, and crater structures after hydrothermal treatment. This process significantly enhances the microporous structure of the coating, with the MoSe 2 film forming a dense and uniform interlocking layer with the PEO lower layer. Dry friction test experiments demonstrate a 33.7% reduction in friction coefficient and a 29% decrease in wear rate compared to the PEO sample, indicating the synergistic effect between the MoSe 2 film and the PEO coating.
To enhance the tribological properties and corrosion resistance of titanium alloys, this study proposes a novel tribological interface structure combining micro-arc oxidation ceramic coatings with MoSe 2 . Comprehensive analysis using X-ray diffractometry, profilometry, energy-dispersive spectroscopy, and scanning electron microscopy was conducted to evaluate the tribological characteristics of this structure under dry friction and liquid lubrication conditions. Electrochemical experiments assessed the corrosion resistance of the structure. The results indicated that under 3 N-2.5 cm/s, oil lubrication, the structure exhibited the best friction-reducing and lubricating performance, with the friction coefficient reduced by 75 %. The synergistic interaction between the low shear force MoSe 2 particles and the TiO 2 -rich ceramic coating formed a lubricating layer on the surface, thereby achieving reduced friction and enhanced wear resistance. Additionally, this structure demonstrated excellent corrosion resistance. This study provides valuable insights for integrating micro-arc oxidation with new materials in engineering applications.
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