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TIF-1 Zn

CRYSTENGCOMM · 2016 ·Vol. 18 ·期 21 ·3842-3849 · IF 3.849

Adsorptive separation performance of 1-butanol onto typical hydrophobic zeolitic imidazolate frameworks (ZIFs)

Chunping Gao,Qi Shi,Jinxiang Dong

The performance of two hydrophobic zeolitic imidazolate frameworks, MAF-6 and TIF-1 Zn, in adsorptive separation of 1-butanol from acetone–butanol–ethanol model fermentation broth was studied and compared to the data reported for ZIF-8. It was found that, in single-component systems, the adsorption capacities of ZIF-8 and MAF-6 were larger than that of TIF-1 Zn, mainly because of their larger pore volume; however, the time necessary to reach equilibrium was shorter when TIF-1 Zn with a larger pore aperture was used. In breakthrough experiments, it was shown that the adsorptive separation mechanism on ZIF-8 and MAF-6 was based on combined thermodynamics and kinetic effects; on TIF-1 Zn, thermodynamic adsorption took place.

CAS / MDL: 96-20-8 1336-21-6 64-17-5 110-82-7 67-64-1 71-36-3 71-43-2 78-83-1

研究领域: 生物工程 · 化学工程

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