阿拉丁SCI论文搜索工具

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY · 2021 · IF 4.098

High pressure investigations on TTF-TCNQ charge-transfer complexes

Bing Han,Ruixiang Ma,Haihua Wang,Mi Zhou

Charge-transfer complexes (CTC) exhibit promising application in scientific field. A prototype CTC (TTF-TCNQ), formed by charge donating (tetrathiafulvalene) and charge accepting (tetracyanoquinodimethane) molecule, was systematically studied by Raman method. By combining Raman and synchrony X-ray diffraction (XRD), we investigated the high-pressure structures of TTF-TCNQ up to 15 GPa, and did not observe any first-order phase transition. Finally, a detailed evolution of structure for TTF-TCNQ, versus pressure, is provided, offering a new pathway to investigate the structural stability of CTC.

CAS / MDL: 1518-16-7

研究领域: 材料科学 · 物理学

✓ 已验证产品关联 DOI PubMed 高影响因子

查看原文查看 PubMed

SYNTHETIC METALS · 2021 · IF 3.266

TTF-TCNQ derived N,S-codoped carbon with multiple macropores for excellent electromagnetic wave adsorption

Jiaoyan Shi,Lipeng Wu,Qingya Sun,Fan Wu,Aming Xie

Elemetal doping is an efficient strategy to adjust the microstructue and electronic property of a carbon material, as a result, shows great potential in the design of novel electromagnetic absorption (EMA) materials. In this work, we report an useful strategy to prepare a N,S co-doped carbon (NSC) using TTF-TCNQ as the precusor, and systematically explore its frequency-depedent dielectric and EMA properties. Different N/S ratios can be tuned by the regulation of pyrolitic temperature. The derived NSC exhibits wonderful EMA performance when the pyrolytic temperature is setted to 700 ℃ with loading ratio of 35 wt%. Efficient absorption can be achieved in the frequency range of 6.4–18 GHz. Moreover, it is determined that the efficient absorption bandwidth gets to 6.5 GHz, while the maximal absorption reaches −46 dB. The EMA mechanism of NSC is considered to be mainly contributed by improved impedance matching realized by macropores, enhanced conductance loss caused by well constructed condutive network, and polarization by N,S doping. This research provides a new idea for development of novel carbon materials for EMA applicaion.

CAS / MDL: 1518-16-7 31366-25-3

研究领域: 材料科学 · 电磁学

✓ 已验证产品关联 DOI 高影响因子

查看原文查看 PubMed

Nano Research · 2023 ·Vol. 16 ·期 12 ·13366-13374 · IF 9.9

Mace-like TTF-TCNQ/HKUST-1 composite structures for rapid NO2 detection: Synergistically induced ultrahigh sensitivity and outstanding selectivity

Lin Chaoxin,Kim Kumchol,Wang Zuochao,Yan Zhuang,Tang Zhiyong,Liu Yaling

Integration and synergy of the unique functions of different components have been developed into one of the most convenient and effective ways to construct the composite advanced materials with collective properties and improved performances. In this work, the mace-like tetrathiafulvalene-tetracyanoquinodimethane (TTF-TCNQ)/HKUST-1 composite structures with single single-crystalline TTF-TCNQ submicrorods covered by ordered HKUST-1 nanosheet arrays were successfully constructed by an efficient TTF-TCNQ seed-mediated growth approach. Impressively, thanks to the synergetic and complementary effects between TTF-TCNQ and HKUST-1, the sensors based on such mace-like TTF-TCNQ/HKUST-1 composite structures not only displayed an experimental detection limit of 10 part per billion (ppb) for NO 2 detection, but also exhibited outstanding selectivity even if the concentration of the interfering gases was 10 times that of NO 2 . Meanwhile, good reproducibility and rapid response were also achieved. This work opens the avenue for creation of novel high-performance sensing materials for application in gas sensing.

研究领域: 材料科学 · 化学传感 · 纳米技术 · 气体传感器

✓ 已验证 DOI 高影响因子

查看原文查看 PubMed

查找使用阿拉丁产品的科研文献

与阿拉丁产品相关的已发表科研成果

热门产品

High pressure investigations on TTF-TCNQ charge-transfer complexes

TTF-TCNQ derived N,S-codoped carbon with multiple macropores for excellent electromagnetic wave adsorption

Mace-like TTF-TCNQ/HKUST-1 composite structures for rapid NO2 detection: Synergistically induced ultrahigh sensitivity and outstanding selectivity