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JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH · 2024 ·Vol. 129 ·期 3 ·e2023JB027306 · IF 3.9

Low δ18O and δ30Si TTG at ca. 2.3 Ga Hints at an Intraplate Rifting Onset of the Paleoproterozoic Supercontinent Cycle

Yanyan Zhou,Mingguo Zhai,Ross N. Mitchell,Peter A. Cawood,Guangyu Huang,Christopher J. Spencer,Mimi Chen,Yibing Li,Taiping Zhao,Tengfei Wu

The start of the Paleoproterozoic supercontinent cycle is typically taken as the initiation of orogenesis at ca. 2.1 Ga leading to the assembly of Earth's first supercontinent, Columbia. However, the dearth of ca. 2.5–2.2 Ga geological records makes it difficult to deduce tectonic factors during the onset of the Paleoproterozoic supercontinent cycle. The petrogenesis of tonalite–trondhjemite–granodiorite (TTG) provides useful proxies for tracing prevailing geodynamic regimes of early continental evolution. However, marked decreases of TTG and other magmatism occurred across the Archean–Paleoproterozoic transition and have previously precluded forming testable hypotheses. Early Paleoproterozoic TTGs have been identified in the North China Craton (NCC) and other cratons, which may represent the last major pulse of TTGs globally. Here we present low δ 18 O and δ 30 Si ca. 2.3 Ga TTGs from the NCC, together with thermodynamic modeling and compilation of stable O and Si isotopes for TTGs globally through time. The ca. 2.3 Ga TTGs were derived from the partial melting of Archean basaltic crust and give lighter average zircon δ 18 O (3.15 ± 0.35‰) and whole-rock δ 30 Si values (−0.17 ± 0.08‰) than most Archean TTGs. Considering coeval mafic-felsic igneous rocks, and lithospheric thinning since ca. 2.5 Ga based on estimated crustal thickness through the Neoarchean–Paleoproterozoic, we posit the onset of an intraplate rifting consistent with the anomalous low-δ 18 O magmatism. Continental rifting of Archean cratons/supercratons plausibly hints at the formation of rifts driving subduction initiation as the veritable onset of the Paleoproterozoic supercontinent cycle. Key Points Ca. 2.3 Ga tonalite–trondhjemite–granodiorite (TTG) in the North China Craton (NCC) shows the affinity of low-pressure (LP) TTGs and contains low zircon δ 18 O and bulk-rock δ 30 Si values Ca. 2.3 Ga low δ 18 O and δ 30 Si TTG and coeval low-δ 18 O magmatism herald the initiation of an intraplate rift setting Such intraplate rifting hints at the formation of rifts driving subduction as the real onset of the Paleoproterozoic supercontinent cycle Plain Language Summary The Earth's first supercontinent, Paleoproterozoic–Mesoproterozoic Columbia, likely began to form during ca. 2.1 Ga (billion years ago) orogenesis. However, the limited record of ca. 2.5–2.2 Ga magmatism makes it difficult to establish how exactly the Paleoproterozoic supercontinent cycle commenced. The tonalite–trondhjemite–granodiorite (TTG) series of felsic rocks forms the backbone of Archean cratons and can provide key constraints on the Earth's early tectonic evolution. Some early Paleoproterozoic TTGs occur in North China and other cratons, which may represent the last major TTG event globally, presenting the possibility to fulfill this role. Here we carry out zircon O and bulk-rock Si isotopic analyses and thermodynamic modeling for these ca. 2.3 Ga TTGs, together with Si-O-Hf data compilation of TTGs globally through time. These ca. 2.3 Ga TTGs show lighter zircon O and bulk-rock Si isotopes than those of Archean TTGs. They might be formed within-plate, associated with lithospheric thinning and mantle-crust remelting to form mafic-felsic magmatism. We propose an intraplate rift setting for this early ca. 2.3 Ga magmatism, which drove the mobilism that led to the subsequent 2.1–1.8 Ga orogenesis and should be posited as the real start of the Paleoproterozoic supercontinent cycle.

研究领域: 地质学 · 地球化学
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POLYMERS FOR ADVANCED TECHNOLOGIES · 2019 ·Vol. 30 ·期 5 ·1259-1268 · IF 2.162

Effects of a semi-bio-based triazine derivative on intumescent flame-retardant polypropylene

Xinjun Wang,Zongbao Wang,Juan Li

A semi-bio-based synergist ( N , N ′, N ″-1, 3, 5-triazine-2, 4, 6-triyltris-glycine [TTG]) was prepared by using glycine and cyanuric chloride. The structure of TTG was characterized by 1 H NMR and Fourier transform infrared spectroscopy. The TTG was applied in polypropylene (PP)/intumescent flame-retardant compounds to improve its flame retardancy. The flame-retardant properties of PP compounds were evaluated by limiting oxygen index and vertical burning tests (UL-94). The results showed that 17 wt% intumescent flame-retardant and 1 wt% TTG makes PP achieve the UL-94 V-0 rating without drippings, and the limiting oxygen index value is increased to 29.5 vol%. The thermal degradation behavior and char morphology of PP compounds were investigated by thermogravimetric analysis and scanning electron microscopy. The results indicated that TTG accelerates the formation of char layer, regulates the porous structure of char layer, and enhances its barrier property. Therefore, the temperatures of PP compound after two ignitions during the UL-94 test are decreased significantly as shown in infrared thermal imaging. In addition, the combustion characteristics of PP compounds were investigated by cone calorimeter. The peak of heat release rate (PHRR) of PP compound is 67% reduced, and the t PHRR is delayed from 223 to 430 seconds, indicates that the combustion risk of PP compound is reduced.

CAS / MDL: 56-40-6 110-82-7
研究领域: 材料科学 · 高分子化学
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