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Understanding Ta as an Efficient Promoter of MgO–SiO2 Catalyst for Conversion of the Ethanol–Acetaldehyde Mixture into 1,3-Butadiene

Jiang Haoxi,Jiang Angjiong,Gao Qiang,Yang Guochao,wang Lingtao

In this work, Ta was firstly reported as an efficient promoter of MgO–SiO 2 for the conversion of ethanol and acetaldehyde to 1,3-butadiene. The doping of Ta into MgO–SiO 2 forms Ta–O–Si bonds and generates more strong Lewis acid sites, which not only promote the aldol condensation reaction but also significantly facilitate the Meerwein–Ponndorf–Verley reduction, the total conversion around 80% which drops to 65% after 24 h. In addition, the catalyst showed desirable stability in 24 h long-term stability evaluation, the selectivity remained stable at 80%. Graphic Abstract