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JOURNAL OF CHEMICAL THERMODYNAMICS · 2020 · IF 2.888

Volumetric properties of n-hexadecane/ethyl octanoate mixtures from 293.15 K to 363.15 K and pressures up to 60 MPa

Xiaojie Wang,Weibiao Du,Xiaopo Wang

The densities of pure ethyl octanoate and n -hexadecane/ethyl octanoate mixtures were measured from 293.15 K to 363.15 K and up to 60 MPa using U -shape vibrating-tube densimeter. The results were correlated as Tait equation, the excess molar volumes, isothermal compressibilities, and isobaric thermal expansivities of the mixtures were calculated and analyzed. In addition, the parameters in the PC-SAFT equation for ethyl octanoate were obtained based on the high-pressure densities obtained in this work and the vapour pressure in the literatures. The densities of the mixtures were predicted by PC-SAFT equation, the absolute average deviations between the experimental results and those calculated were less than 0.52%.

CAS / MDL: 544-76-3 106-32-1

研究领域: 物理化学 · 热力学

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JOURNAL OF MOLECULAR LIQUIDS · 2020 · IF 5.065

Liquid viscosities of ethyl caprylate and ethyl caprate at elevated temperatures and pressures

Xiaojie Wang,Weibiao Du,Xiaopo Wang

In this work, the high-pressure liquid viscosities of ethyl caprylate and ethyl caprate were measured at the temperatures from 303 K to 362 K and pressures up to 30 MPa. The measurements were carried out based the falling-cylinder viscosity measurement system which was established in our laboratory. The combined expanded relative uncertainty of the present measurement was <0.03 with a confidence level of 0.95. The high-pressure viscosity values were correlated with Andrade-Tait equation. The average relative deviation between experimental data and calculated results from Andrade-Tait equation for ethyl caprylate and ethyl caprate was 0.38% and 0.73%, respectively. The maximum relative deviation was 1.32% and 1.96%, respectively.

CAS / MDL: 106-32-1 110-38-3

研究领域: 化学工程 · 物理化学

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