Excitation wavelength-dependent lanthanide-disalicylaldehyde coordination hybrid capable of distinguishing D2O from H2O
The increasing demands in fields of anti-counterfeiting, fluorescence analysis, clinical therapy and LED illumination are urgently eager for more excellent optically switchable luminescent materials with the stable and multimodal fluorescence in single-component matrix. Herein, the lanthanide-disalicylaldehyde coordination hybrid H 2 Q j4 /Tb x Eu y is proposed as an efficient luminescent matrix to connect terbium sensibilization with ESIPT (excited-state intramolecular proton transfer) effects, and three multi-emission hybrids are finally designed and synthesized by regulating Tb 3+ and Eu 3+ ratios. Surprisingly, the H 2 Q j4 /Tb 0.91 Eu 0.09 shows the excitation wavelength-dependent luminescence in solution which originates from two energy transfer ways of terbium sensibilization effect. It exhibits green and red lights under the 369 and 394 nm UV lamp, respectively. Three hybrids are further used as lab-on-a-molecule fluorescent probes to perform multianalyte detection for various solvents by selected fluorescent sensing channels. By means of PCA (principal component analysis) and HCA (hierarchical cluster analysis), all of them can successfully detect and discriminate17 common solvents, especially the H 2 O and D 2 O. Moreover, the H 2 Q j4 /Tb 0.91 Eu 0.09 also shows the wide linear responses of H 2 O content in D 2 O, discrimination of two-component solvent mixtures , hygroscopicity evaluation of D 2 O and information encryption which will advance the progress of multimodal luminescent materials and multianalyte chemosensors .
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