A novel Tb3+ and Eu3+ co-doped dual-emitting phosphate K3SrBi(P2O7)2 phosphor for application in FIR thermometers
Rare earth co-doped phosphor for fluorescence intensity ratio (FIR) thermometer has gained increasing attention in recent years. Herein, the novel Tb 3+ and Eu 3+ co-doped K 3 SrBi(P 2 O 7 ) 2 (KSBP) phosphate phosphors were reported. The crystal structure of the title phosphor was determined using Rietveld refinement and proved to have a three-dimensional structure. The time-resolved spectroscopy reveals that there is almost no energy transfer between Tb 3+ and Eu 3+ . More importantly, Tb 3+ and Eu 3+ emissions show different thermal quenching behaviors, which claims the potential of this material for application in optical thermometer. The FIR of the typical KSBP:0.02Tb3+,0.04Eu3+ sample demonstrates a polynomial relationship as a function of temperature and the absolute and relative sensitivity are 0.025 K –1 and 0.59%/K, respectively. In general, our study reports a novel and potential KSBP:Tb 3+ ,Eu 3+ phosphate phosphor that is promising for use in high-sensitive FIR thermometers.
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